Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3

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	Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3
	Chu LL(储玲玲) ; Qing FL(卿凤翎)
刊名	J. Am. Chem. Soc.
	2010
卷号	132 期号:21 页码:7262-7263
ISSN号	0002-7863
其他题名	Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3
通讯作者	卿凤翎
英文摘要	An efficient copper-mediated trifluoromethylation of terminal alkynes with nucleophilic trifluoromethylating reagent (Me3SiCF3) was developed. Both aromatic alkynes and aliphatic alkynes were effective, and a variety of functionalities such as amino, -OMe, -CO2Et, -Br, and -NO2 were tolerated under the reaction conditions. This reaction provides a general, straightforward, and practically useful method to prepare trifluoromethylated acetylenes.
学科主题	氟化学 ; 金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ja102175w
语种	英语
WOS记录号	WOS:000278190600015
公开日期	2013-02-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/17677]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Chu LL,Qing FL. Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3[J]. J. Am. Chem. Soc.,2010,132(21):7262-7263.
APA	储玲玲,&卿凤翎.(2010).Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3.J. Am. Chem. Soc.,132(21),7262-7263.
MLA	储玲玲,et al."Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3".J. Am. Chem. Soc. 132.21(2010):7262-7263.