Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates

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	Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates
	Xu J(徐军) ; Qiu XL(邱小龙) ; Qing FL(卿凤翎)
刊名	Beilstein J. Org. Chem.
	2008
卷号	4 期号:18 页码:1-5
ISSN号	1860-5397
其他题名	Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates
通讯作者	卿凤翎
英文摘要	We present a mechanistic investigation of Pd-catalyzed allylic substitution of cyclic gem-difluorinated carbonates 1 and 4, previously employed in the synthesis of 3',3'-difluoro-2'-hydroxymethyl-4',5'-unsaturated carbocyclic nucleosides in 17 steps. The substitution features a reversal of regioselectivity caused by fluorine.
学科主题	氟化学 ; 金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.3762/bjoc.4.18
语种	英语
WOS记录号	WOS:000256827300001
公开日期	2013-02-22
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/17639]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Xu J,Qiu XL,Qing FL. Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates[J]. Beilstein J. Org. Chem.,2008,4(18):1-5.
APA	徐军,邱小龙,&卿凤翎.(2008).Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates.Beilstein J. Org. Chem.,4(18),1-5.
MLA	徐军,et al."Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates".Beilstein J. Org. Chem. 4.18(2008):1-5.