Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates | |
Xu J(徐军) ; Qiu XL(邱小龙) ; Qing FL(卿凤翎) | |
刊名 | Beilstein J. Org. Chem.
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2008 | |
卷号 | 4期号:18页码:1-5 |
ISSN号 | 1860-5397 |
其他题名 | Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates |
通讯作者 | 卿凤翎 |
英文摘要 | We present a mechanistic investigation of Pd-catalyzed allylic substitution of cyclic gem-difluorinated carbonates 1 and 4, previously employed in the synthesis of 3',3'-difluoro-2'-hydroxymethyl-4',5'-unsaturated carbocyclic nucleosides in 17 steps. The substitution features a reversal of regioselectivity caused by fluorine. |
学科主题 | 氟化学 ; 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.3762/bjoc.4.18 |
语种 | 英语 |
WOS记录号 | WOS:000256827300001 |
公开日期 | 2013-02-22 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/17639] ![]() |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
推荐引用方式 GB/T 7714 | Xu J,Qiu XL,Qing FL. Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates[J]. Beilstein J. Org. Chem.,2008,4(18):1-5. |
APA | 徐军,邱小龙,&卿凤翎.(2008).Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates.Beilstein J. Org. Chem.,4(18),1-5. |
MLA | 徐军,et al."Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates".Beilstein J. Org. Chem. 4.18(2008):1-5. |
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