Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes

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	Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes
	Zhu SF(祝诗发) ; Liao YX(廖远熹) ; Zhu SZ(朱仕正)
刊名	Org. Lett.
	2004
卷号	6 期号:3 页码:377-380
ISSN号	1523-7060
其他题名	过渡金属催化醛的偶联形成完全反式烯烃
通讯作者	朱仕正
英文摘要	Rh-2(OAC)(4) catalyzed the formation of exclusively trans fluorinated alkenes from aldehydes and pentafluorobenzaldehyde tosylhydrazone salts, which were readily prepared from pentafluorobenzaldehyde using the Bamford-Stevens reaction. A series of pentafluorophenyl-containing alkenes were synthesized from aldehydes in moderate to good yields under mild reaction conditions in a one-pot reaction. It is the first report of coupling two different aldehydes to form exclusively trans alkenes.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ol036197s
语种	英语
WOS记录号	WOS:000188596200018
公开日期	2013-01-18
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14328]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Zhu SF,Liao YX,Zhu SZ. Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes[J]. Org. Lett.,2004,6(3):377-380.
APA	祝诗发,廖远熹,&朱仕正.(2004).Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes.Org. Lett.,6(3),377-380.
MLA	祝诗发,et al."Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes".Org. Lett. 6.3(2004):377-380.