Reactions of fluoroalkanesulfonyl azides with trimethylsilyl enol ethers

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 中科院有机氟化学重点实验室

	Reactions of fluoroalkanesulfonyl azides with trimethylsilyl enol ethers
	Xu Y(许勇) ; Xu GL(许国林) ; Zhu SZ(朱仕正) ; Zhu GY(朱光宇) ; Jia YS(贾一四) ; Huang QC(黄其辰)
刊名	J. Fluor. Chem.
	1999
卷号	96 页码:79-85
ISSN号	0022-1139
其他题名	氟烷砜基叠氮与三甲基烯醇硅醚的反应研究
通讯作者	朱仕正
英文摘要	Reactions of per(poly)-fluoroalkanesulfonyl azides R=fSO=2N=3 with trimethylsily enol ethers RCH=C(H)OSiMe=3 (R=1=tBu, Ph)afforded α－[N-(fluoroalkanesulfonyl)] amino ketones RC(O)CH=2NHSO=2R=f in good yields. The cycloanalog 1-cyclohexenyl trimethylsilyl ether reacted with the azides to give one-carbon ring-contracted product N-fluoroalkanesulfonyl cyclopentanecarboxamides, c -C=5H=11CONH-SO=2R=f. In the case of 1-cyclooctenyl trimethylsilyl ether, however, two products α－[N-(fluoroalkane sulfonyl)amine cyclooctanones and c-C=7H=13CONHSO=2R=f were obtained.
学科主题	有机氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/S0022-1139(99)00009-3
语种	英语
WOS记录号	WOS:000081013400016
公开日期	2013-01-18
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14216]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Xu Y,Xu GL,Zhu SZ,et al. Reactions of fluoroalkanesulfonyl azides with trimethylsilyl enol ethers[J]. J. Fluor. Chem.,1999,96:79-85.
APA	许勇,许国林,朱仕正,朱光宇,贾一四,&黄其辰.(1999).Reactions of fluoroalkanesulfonyl azides with trimethylsilyl enol ethers.J. Fluor. Chem.,96,79-85.
MLA	许勇,et al."Reactions of fluoroalkanesulfonyl azides with trimethylsilyl enol ethers".J. Fluor. Chem. 96(1999):79-85.