Study on the reactions of fluoroalkanesulfonyl azides with pyridine and its derivatives

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	Study on the reactions of fluoroalkanesulfonyl azides with pyridine and its derivatives
	Xu Y(许勇) ; Zhu SZ(朱仕正)
刊名	Tetrahedron
	1999
卷号	55 页码:13725-13734
ISSN号	0040-4020
其他题名	全氟(及多氟)烷基磺酰叠氮与吡啶及其衍生物的反应研究
通讯作者	朱仕正
英文摘要	The thermal reactions of fluoroalkanesulfonyl azides R=fSO=2N=3 1 with pyridine and its derivatives have been investigated in detail. In many cases, N-fluoroalkanesulfonyl pyridinium imides Y+-N SO=2R=f(Y: pyridine, 3-picoline, 3,5,-lutidine and quinoline) and the hydrogen abstaction products F=fSO=2NH=2 were obtained. 2-Picoline and 4-picoline reacted with 1 to give R=fSO=2NH=2 exclusively. Interstingly, in thereaction of azides 1c IC=2F=4OC=2F=4SO=2N=3 with 4-picoline or quinoline, theω-iodine of the azide was substituted to form A=rC=2F=4OC=2F=4SO=2NH=2.
学科主题	有机氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/S0040-4020(99)00856-X
语种	英语
WOS记录号	WOS:000083545900007
公开日期	2013-01-18
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/14214]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Xu Y,Zhu SZ. Study on the reactions of fluoroalkanesulfonyl azides with pyridine and its derivatives[J]. Tetrahedron,1999,55:13725-13734.
APA	许勇,&朱仕正.(1999).Study on the reactions of fluoroalkanesulfonyl azides with pyridine and its derivatives.Tetrahedron,55,13725-13734.
MLA	许勇,et al."Study on the reactions of fluoroalkanesulfonyl azides with pyridine and its derivatives".Tetrahedron 55(1999):13725-13734.