Thermal rearrangement of substituted difluoro(methylene)cyclopropane

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 中科院有机氟化学重点实验室

	Thermal rearrangement of substituted difluoro(methylene)cyclopropane
	Hang XC(杭晓春) ; Gu WP(辜伟鹏) ; Chen QY(陈庆云) ; Xiao JC(肖吉昌) ; Xu WG(徐卫国) ; Liu SB(刘述斌)
刊名	J. Fluor. Chem.
	2011
卷号	132 期号:1 页码:63-67
ISSN号	0022-1139
其他题名	取代的二氟(亚甲基)环丙烷在加热条件下的重排反应
通讯作者	肖吉昌 ; 刘述斌
英文摘要	Both experimental and computational approaches have been employed in the present work to investigate the thermal conversion of substituted difluoro(methylene)cyclopropanes (F2MCP) E-1,1-difluoro-2,2-dimethyl-3-tosylmethylene cyclopropane 1, to the thermodynamically more stable F2MCP products, 1,1-difluoro-2-tosyl-3-(propan-2-ylidene)cyclopropane 2, and 1-(3-(difluoromethylene)-2,2-dimethylcyclopropylsulfonyl)-4-methylbenzen e 3. The X-ray crystal structure has been obtained for both 1 and 2, respectively, based on which theoretical analyses on their structure and stability have been carried out. Possible reaction mechanisms are proposed. (c) 2010 Elsevier B.V. All rights reserved.
学科主题	有机氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.jfluchem.2010.11.007
语种	英语
WOS记录号	WOS:000286699400010
公开日期	2013-01-17
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/13706]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Hang XC,Gu WP,Chen QY,et al. Thermal rearrangement of substituted difluoro(methylene)cyclopropane[J]. J. Fluor. Chem.,2011,132(1):63-67.
APA	杭晓春,辜伟鹏,陈庆云,肖吉昌,徐卫国,&刘述斌.(2011).Thermal rearrangement of substituted difluoro(methylene)cyclopropane.J. Fluor. Chem.,132(1),63-67.
MLA	杭晓春,et al."Thermal rearrangement of substituted difluoro(methylene)cyclopropane".J. Fluor. Chem. 132.1(2011):63-67.