A facile and potent synthesis of meso,meso-linked porphyrin arrays using iodine(III) reagents

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	A facile and potent synthesis of meso,meso-linked porphyrin arrays using iodine(III) reagents
	Jin LM(金利美) ; Chen L(陈亮) ; Yin JJ(尹娟娟) ; Guo CC(郭灿城) ; Chen QY(陈庆云)
刊名	Eur. J. Org. Chem.
	2005
期号	18 页码:3994-4001
ISSN号	1434-193X
其他题名	用三价碘试剂方便地合成各种meso,meso-连接的卟啉
通讯作者	郭灿城 ; 陈庆云
英文摘要	The synthesis of meso,meso-linked fluoroalkylporphyrin arrays has been accomplished, in excellent yields, by the simple treatment of a CHCL3 solution of zincated 5-fluoroalkyl10,20-diarylporphyrins (where fluoroalkyl = CF3, ClC2F4, n=ClC4F8, n-C6F13, etc.) with iodine(III) reagents such as PhI(OCO-CF3)(2) (PIFA, also named as bis(trifluoroacetoxy)iodolbenzene) or PhI(OAc)(2) (PIDA), For nonfluorinated zincated 5-substituted-10 20-diarylporphyrins (where substituent = phenyl, 4-methoxyphenyl, 4-methylphenyl, etc.) the similar Coupling reactions also proceed fast and (quantitatively. Moreover, various 15-unsubstituted metalloporphyrins Can also be coupled in high yields. (c) Wiley-WCH Verlagh GmbH & Co, KGaA, 69451 Weinheim, Germany, 2005.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/ejoc.200500255
语种	英语
WOS记录号	WOS:000232068100016
公开日期	2013-01-17
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/13586]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Jin LM,Chen L,Yin JJ,et al. A facile and potent synthesis of meso,meso-linked porphyrin arrays using iodine(III) reagents[J]. Eur. J. Org. Chem.,2005(18):3994-4001.
APA	金利美,陈亮,尹娟娟,郭灿城,&陈庆云.(2005).A facile and potent synthesis of meso,meso-linked porphyrin arrays using iodine(III) reagents.Eur. J. Org. Chem.(18),3994-4001.
MLA	金利美,et al."A facile and potent synthesis of meso,meso-linked porphyrin arrays using iodine(III) reagents".Eur. J. Org. Chem. .18(2005):3994-4001.