3,3-Difluoro-1-iodocyclopropenes: A simple synthesis and their reactions

	3,3-Difluoro-1-iodocyclopropenes: A simple synthesis and their reactions
	Xu W(徐伟) ; Chen QY(陈庆云)
刊名	J. Org. Chem.
	2002
卷号	67 期号:26 页码:9421-9427
ISSN号	0022-3263
其他题名	3,3-二氟-1-碘环丙烯: 合成和反应
通讯作者	陈庆云
英文摘要	The [1+2] cycloaddition reaction of 1-iodoalkynes with difluorocarbene, generated from the decomposition of FSO^2CF^2COOSiMe^3 in diglyme in the presence of 10 mol% NaF at 120℃, gives 3,3-difluoro-1-iodocyclopropenes in good yields. These new iodides can be triflroromethylated and functionalized via the Heck reaction. The unusual hydrolytic reactions of the iodides under acidic conditions was also investigatd.
学科主题	有机氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jo020431v
语种	英语
WOS记录号	WOS:000180072300039
公开日期	2013-01-17
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/13556]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
推荐引用方式 GB/T 7714	Xu W,Chen QY. 3,3-Difluoro-1-iodocyclopropenes: A simple synthesis and their reactions[J]. J. Org. Chem.,2002,67(26):9421-9427.
APA	徐伟,&陈庆云.(2002).3,3-Difluoro-1-iodocyclopropenes: A simple synthesis and their reactions.J. Org. Chem.,67(26),9421-9427.
MLA	徐伟,et al."3,3-Difluoro-1-iodocyclopropenes: A simple synthesis and their reactions".J. Org. Chem. 67.26(2002):9421-9427.