Rapid assembly of anti-1,3-diol units with 2-quaternary carbon stereocenter via samarium diiodide-promoted tandem Aldol/Evans-Tishchenko reaction

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	Rapid assembly of anti-1,3-diol units with 2-quaternary carbon stereocenter via samarium diiodide-promoted tandem Aldol/Evans-Tishchenko reaction
	Sun XW(孙兴文) ; Xu MH(徐明华) ; Lin GQ(林国强)
刊名	Tetrahedron Lett.
	2009
卷号	50 期号:26 页码:3381-3384
ISSN号	0040-4039
其他题名	Rapid assembly of anti-1,3-diol units with 2-quaternary carbon stereocenter via samarium diiodide-promoted tandem Aldol/Evans-Tishchenko reaction
通讯作者	徐明华 ; 林国强
英文摘要	An efficient and practical method for highly diastereoselective synthesis of 2-quaternary anti-1,3-diol units With three adjacent stereogenic carbon centers has been developed. The reactions proceed regiospecifically at room temperature via samarium diiodide-promoted tandem Aldol condensation and Evans-Tishchenko reduction. The relative stereochemistry of the resulting 1,3-diol monoesters is identified by X-ray crystallography. (C) 2009 Elsevier Ltd. All rights reserved.
学科主题	天然产物有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tetlet.2009.02.104
语种	英语
WOS记录号	WOS:000267070700069
公开日期	2013-02-20
内容类型	期刊论文
源URL	[http://202.127.28.38/handle/331003/16693]
专题	上海有机化学研究所_中科院天然产物有机化学重点实验室
推荐引用方式 GB/T 7714	Sun XW,Xu MH,Lin GQ. Rapid assembly of anti-1,3-diol units with 2-quaternary carbon stereocenter via samarium diiodide-promoted tandem Aldol/Evans-Tishchenko reaction[J]. Tetrahedron Lett.,2009,50(26):3381-3384.
APA	孙兴文,徐明华,&林国强.(2009).Rapid assembly of anti-1,3-diol units with 2-quaternary carbon stereocenter via samarium diiodide-promoted tandem Aldol/Evans-Tishchenko reaction.Tetrahedron Lett.,50(26),3381-3384.
MLA	孙兴文,et al."Rapid assembly of anti-1,3-diol units with 2-quaternary carbon stereocenter via samarium diiodide-promoted tandem Aldol/Evans-Tishchenko reaction".Tetrahedron Lett. 50.26(2009):3381-3384.