Samarium diiodide-promoted electrophilic amination of ketone enolates: efficient synthesis of quaternary carbon-containing alpha-aminated ketones | |
Sun XW(孙兴文) ; WANG WEI ; Xu MH(徐明华) ; Lin GQ(林国强) | |
刊名 | Tetrahedron Lett.
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2008 | |
卷号 | 49期号:40页码:5807-5809 |
ISSN号 | 0040-4039 |
其他题名 | Samarium diiodide-promoted electrophilic amination of ketone enolates: efficient synthesis of quaternary carbon-containing alpha-aminated ketones |
通讯作者 | 徐明华 ; 林国强 |
英文摘要 | An efficient and practical electrophilic amination method that allows the preparation of useful quaternary carbon-containing alpha-aminoketones was developed. The reaction proceeds regiospecifically via a samarium enolate intermediate at room temperature in the presence of mild reducing agent SmI2. Unlike the most reported lithium enolate cases, this new amination method does not require the use of strong base such as BuLi or LDA. (C) 2008 Elsevier Ltd. All rights reserved. |
学科主题 | 有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tetlet.2008.07.123 |
语种 | 英语 |
WOS记录号 | WOS:000259537800027 |
公开日期 | 2013-02-20 |
内容类型 | 期刊论文 |
源URL | [http://202.127.28.38/handle/331003/16665] ![]() |
专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
推荐引用方式 GB/T 7714 | Sun XW,WANG WEI,Xu MH,et al. Samarium diiodide-promoted electrophilic amination of ketone enolates: efficient synthesis of quaternary carbon-containing alpha-aminated ketones[J]. Tetrahedron Lett.,2008,49(40):5807-5809. |
APA | 孙兴文,WANG WEI,徐明华,&林国强.(2008).Samarium diiodide-promoted electrophilic amination of ketone enolates: efficient synthesis of quaternary carbon-containing alpha-aminated ketones.Tetrahedron Lett.,49(40),5807-5809. |
MLA | 孙兴文,et al."Samarium diiodide-promoted electrophilic amination of ketone enolates: efficient synthesis of quaternary carbon-containing alpha-aminated ketones".Tetrahedron Lett. 49.40(2008):5807-5809. |
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