Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines | |
Yao Ming; Lu Chong-Dao | |
刊名 | ORGANIC LETTERS |
2011 | |
卷号 | 13期号:10页码:2782-2785 |
ISSN号 | 1523-7060 |
通讯作者 | Lu, CD |
英文摘要 | Three-component coupling reactions of sulfonylimidates, silyl glyoxylates and N-tert-butanesulfinyl aldimines efficiently provide cyclic N-sulfonylamiclines containing free endocyclic N-H. The formation of two C-C bonds (contiguous stereogenic carbons), one O-Si bond, and one C-N bond, together with the cleavage of the chiral auxiliary (tert-butanesulfinyl group), occurs with excellent chemoselectivity, diastereoselectivity, and enantioselectivity in this one-pot cascade transformation. |
学科主题 | Chemistry |
收录类别 | SCI |
WOS记录号 | WOS:000290465800069 |
公开日期 | 2012-11-29 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/1661] |
专题 | 新疆理化技术研究所_资源化学研究室 |
作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Yao Ming,Lu Chong-Dao. Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines[J]. ORGANIC LETTERS,2011,13(10):2782-2785. |
APA | Yao Ming,&Lu Chong-Dao.(2011).Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines.ORGANIC LETTERS,13(10),2782-2785. |
MLA | Yao Ming,et al."Three-Component Reactions of Sulfonylimidates, Silyl Glyoxylates and N-tert-Butanesulfinyl Aldimines: An Efficient, Diastereoselective, and Enantioselective Synthesis of Cyclic N-Sulfonylamidines".ORGANIC LETTERS 13.10(2011):2782-2785. |
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