syntheses, structures and properties of three nonmetal borates with     salicylic acid and organic amines

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines
	Yang Yun; Pan Shilie; Hou Xueling; Guo Jing; Li Feng; Han Jian; Guo Jixi; Jia Dianzeng
刊名	INORGANICA CHIMICA ACTA
	2011
卷号	365 期号:1 页码:20-24
关键词	Salicylic acid Borate Organic amino Crystal structures Fluorescence
ISSN号	0020-1693
通讯作者	Pan, SL
中文摘要	Three new borates containing nonmetal compounds, C(4)H(12)NBO(4)(C(7)H4(O))(2) (1), C(8)H(20)NBO(4)(C(7)H(4)O)2 (2) and C(6)H(18)N(2)(0.5)BO(4)(C(7)H(4)O)(2) (3) have been prepared, aiming at the formation of extended supramolecular networks with organic-inorganic hybrid materials of salicylic acid and boric acid. The corresponding compounds have been characterized by chemical and spectroscopic techniques. X-ray diffraction analyses of available single crystals revealed that the molecular structures of the three compounds have the same isolated BO(4)(C(7)H(4)O)(2) anion. The BO(4)(C(7)H(4)O)(2) anion with a distorted BO(4) tetrahedron is formed by bidentate coordination of the B atom to two salicylic acid molecules via the O atoms of the central carboxyl and alpha-hydroxyl groups. The three compounds display violet luminescence with emission maxima around 365 nm.
学科主题	Chemistry
收录类别	SCI
资助信息	National Natural Science Foundation of China 50802110; "One Hundred Talents Project Foundation Program" of Chinese Academe of Sciences; "Western Light Joint Scholar Foundation" Program of Chinese Academe of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars; State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; Xinjiang Uygur Autonomous
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1675]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China; Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
推荐引用方式 GB/T 7714	Yang Yun,Pan Shilie,Hou Xueling,et al. syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines[J]. INORGANICA CHIMICA ACTA,2011,365(1):20-24.
APA	Yang Yun.,Pan Shilie.,Hou Xueling.,Guo Jing.,Li Feng.,...&Jia Dianzeng.(2011).syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines.INORGANICA CHIMICA ACTA,365(1),20-24.
MLA	Yang Yun,et al."syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines".INORGANICA CHIMICA ACTA 365.1(2011):20-24.