Synthesis, structure and properties of Pb2Bi2AlB3O11

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Synthesis, structure and properties of Pb2Bi2AlB3O11
	Li Junjie; Pan Shilie; Zhao Wenwu; Tian Xuelin; Han Jian; Fan Xiaoyun
刊名	Journal of Molecular Structure
	2011
卷号	994 期号:1-3 页码:321-324
关键词	Pb2Bi2AlB3O11 Borate Structure determination Single-crystal diffraction
ISSN号	222860
通讯作者	Pan, SL
中文摘要	Single crystals of Pb2Bi2AlB3O 11 were grown from a PbO/Bi2O3/Al 2O3/H3BO3/PbF2 flux. The single-crystal X-ray structural analysis showed that Pb2Bi 2AlB3O11 crystallizes in the monoclinic space group C2/c (No. 15) with a = 17.263(2) A˚, b = 8.7322(11) A˚, c = 6.8081(9) A˚, α = 90°, β = 90.566(2)°, γ = 90°, Z = 4 and R1 = 0.0393, wR2 = 0.1013. Its structure may be described as three-dimensional frameworks formed of (1 0 0) [Pb6Bi6Al3O6]∞ layers stacked along a-axis. The layers are interconnected via BO3 groups. The IR spectrum further confirmed the presence of BO3 groups in the structure. The thermal analysis suggests that Pb2Bi 2AlB3O11 is a congruently melting compound.
学科主题	Chemistry
收录类别	SCI
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1454]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Li Junjie,Pan Shilie,Zhao Wenwu,et al. Synthesis, structure and properties of Pb2Bi2AlB3O11[J]. Journal of Molecular Structure,2011,994(1-3):321-324.
APA	Li Junjie,Pan Shilie,Zhao Wenwu,Tian Xuelin,Han Jian,&Fan Xiaoyun.(2011).Synthesis, structure and properties of Pb2Bi2AlB3O11.Journal of Molecular Structure,994(1-3),321-324.
MLA	Li Junjie,et al."Synthesis, structure and properties of Pb2Bi2AlB3O11".Journal of Molecular Structure 994.1-3(2011):321-324.