synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10
	Wu Hongping; Pan Shilie; Yu Hongwei; Chen Zhaohui; Zhang Fangfang
刊名	Solid State Sciences
	2012
卷号	14 期号:7 页码:936-940
关键词	K3ZnB5O10 Single crystal growth X-ray diffraction Optical properties
ISSN号	12932558
通讯作者	Pan, SL
中文摘要	A new compound, K3ZnB5O10, has been synthesized by solid-state reaction. It crystallizes in the monoclinic system, space group P21/n with unit-cell parameters a = 7.6391(5) A˚, b = 19.2304(13) A˚, c = 7.6905(5) A˚, β = 116.698(4)° and Z = 4. The structure of the compound is solved by the direct methods and refined to R1 = 0.0286 and wR2 = 0.0600. K3ZnB5O10 contains a two-dimensional ZnB5O10 layer, which forms by connecting isolated double ring [B5O10] groups and ZnO4 tetrahedra. The K atoms filling in the interlayer and intralayer link the layers together. Functional groups presented in the sample were identified by FTIR spectrum. UV-vis-NIR diffuse reflectance spectrum exhibits ultraviolet cutoff edge is about 190 nm. The DSC analysis proves that K 3ZnB5O10 is a congruently melting compound.
学科主题	Chemistry ; Physics
收录类别	SCI
公开日期	2012-11-29
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/1382]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China; Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
推荐引用方式 GB/T 7714	Wu Hongping,Pan Shilie,Yu Hongwei,et al. synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10[J]. Solid State Sciences,2012,14(7):936-940.
APA	Wu Hongping,Pan Shilie,Yu Hongwei,Chen Zhaohui,&Zhang Fangfang.(2012).synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10.Solid State Sciences,14(7),936-940.
MLA	Wu Hongping,et al."synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10".Solid State Sciences 14.7(2012):936-940.