Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes

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	Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes
	Jiao TF(焦体峰) ; Yang N(杨娜) ; Zhou JX(周靖欣)
刊名	Materials Science Forum
	2011
卷号	694 页码:667-671
关键词	Schiff base Metal complex Liquid crystal Spectral measurement
ISSN号	1662-9752
通讯作者	焦体峰
中文摘要	Some Schiff base compounds with aromatic substituted groups and their Cu-complexes have been designed and synthesized from the reaction of aromatic amines with salicylaldehyde. It has been found that depending on the molecular structures and substituted groups, the formed Schiff base compounds showed different properties, indicating distinct regulation of molecular design. UV and IR data confirmed commonly the formation of Schiff base and coordination with Cu(II) ions, as well as aromatic segment in molecular structures. In addition, the process of ex situ coordination seemed to change differently along with adding time, which could be ascribable to the presence of distinct substituted group and change of reaction activity. The spectral difference is mainly attributed to molecular structures, formation of Schiff base group and different substituted groups. The present results have showed that the special properties of Schiff base compounds could be turned by modifying molecular structures and substituted groups, which show potential application in fields of functional material fields such as liquid crystal and catalysts.
学科主题	材料科学与物理化学
收录类别	SCI
资助信息	the National Natural Science Foundation of China (NO.20903078);the Natural Science Foundation of Hebei Province (NO.B2009000347);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (NO.CPRC020);the Open Foundation of State Key Laboratory of Solid Lubrication (NO.1002);the Scientific Research Plan of Education Department of Hebei Province (NO.Z2009146);the Doctoral Foundation of Yanshan University (NO.B360)
语种	英语
公开日期	2012-09-24
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/793]
专题	兰州化学物理研究所_固体润滑国家重点实验室
推荐引用方式 GB/T 7714	Jiao TF,Yang N,Zhou JX. Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes[J]. Materials Science Forum,2011,694:667-671.
APA	焦体峰,杨娜,&周靖欣.(2011).Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes.Materials Science Forum,694,667-671.
MLA	焦体峰,et al."Research on some Schiff base compounds with aromatic substituted groups and their Cu-complexes".Materials Science Forum 694(2011):667-671.