Noyori’s Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio- and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins | |
Ju YD(鞠亚东); Xu LW(徐利文); Li L(李莉); Lai GQ(来国桥); Qiu HY(邱化玉); Jiang JX(蒋剑雄); Lu YX(卢一新) | |
刊名 | Tetrahedron Letters
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2008 | |
卷号 | 49页码:6773-6777 |
关键词 | Primary amine Dual activation Michael addition Organocatalysis |
ISSN号 | 0040-4039 |
通讯作者 | 徐利文 |
中文摘要 | Noyori’s Ts-DPEN ligand bearing an amino sulfonamide moiety and with a primary amino group on a chiral scaffold was found to be a simple and efficient bifunctional organocatalyst for the asymmetric Michael addition of 1,3-dicarbonyl compounds to nitroolefins, which gave highly functional Michael adduct with quaternary stereocenters in good enantioselectivities (up to 84%ee) and dr (up to 5.7:1 dr). |
学科主题 | 物理化学 |
收录类别 | SCI |
资助信息 | Hangzhou Normal University;the National Nature Science Foundation of China (Project No. 20572114) |
语种 | 英语 |
公开日期 | 2012-11-09 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/1979] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
推荐引用方式 GB/T 7714 | Ju YD,Xu LW,Li L,et al. Noyori’s Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio- and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins[J]. Tetrahedron Letters,2008,49:6773-6777. |
APA | Ju YD.,Xu LW.,Li L.,Lai GQ.,Qiu HY.,...&Lu YX.(2008).Noyori’s Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio- and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins.Tetrahedron Letters,49,6773-6777. |
MLA | Ju YD,et al."Noyori’s Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio- and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins".Tetrahedron Letters 49(2008):6773-6777. |
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