Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode | |
Xia CG(夏春谷)![]() ![]() ![]() ![]() | |
刊名 | Dalton Transactions
![]() |
2008 | |
页码 | 5957-5961 |
ISSN号 | 1477-9226 |
通讯作者 | 夏春谷 ; 孙伟 |
中文摘要 | The imitative synthesis of the ionic liquid [bmim][Co(CO)4], carried out in organic solvents instead of water, produced an unexpected liquid complex with partial crystallization. The resulting solid was confirmed to be the novel hetero-cation salt, [bmim]K[Co(CO)4]2 (1) and a crystallographic investigation revealed an extremely unusual (CO)7–K coordination mode. When the organic cation was replaced by [C4Py]+, similar crystallization was also obtained, forming [C4Py]K[Co(CO)4]2 (2), which has an analogous structure. Both of these cases indicate an interesting influence that these organic cations have on the crystallization of organometallic structures that yields new structural examples. |
学科主题 | 清洁催化与生物转化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (projects 20533080;20625308);the Chinese Academy of Sciences |
语种 | 英语 |
WOS记录号 | WOS:000260486500017 |
公开日期 | 2012-11-09 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/1970] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
通讯作者 | Xia CG(夏春谷); Sun W(孙伟); Sun W(孙伟) |
推荐引用方式 GB/T 7714 | Xia CG,Sun W,Sun W,et al. Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode[J]. Dalton Transactions,2008:5957-5961. |
APA | 夏春谷,孙伟,孙伟,&胡斌.(2008).Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode.Dalton Transactions,5957-5961. |
MLA | 夏春谷,et al."Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode".Dalton Transactions (2008):5957-5961. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论