Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > OSSO国家重点实验室

	Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode
	Xia CG(夏春谷); Sun W(孙伟); Sun W(孙伟); Hu B(胡斌)
刊名	Dalton Transactions
	2008
页码	5957-5961
ISSN号	1477-9226
通讯作者	夏春谷 ; 孙伟
中文摘要	The imitative synthesis of the ionic liquid [bmim][Co(CO)4], carried out in organic solvents instead of water, produced an unexpected liquid complex with partial crystallization. The resulting solid was confirmed to be the novel hetero-cation salt, [bmim]K[Co(CO)4]2 (1) and a crystallographic investigation revealed an extremely unusual (CO)7–K coordination mode. When the organic cation was replaced by [C4Py]+, similar crystallization was also obtained, forming [C4Py]K[Co(CO)4]2 (2), which has an analogous structure. Both of these cases indicate an interesting influence that these organic cations have on the crystallization of organometallic structures that yields new structural examples.
学科主题	清洁催化与生物转化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (projects 20533080;20625308);the Chinese Academy of Sciences
语种	英语
WOS记录号	WOS:000260486500017
公开日期	2012-11-09
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/1970]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xia CG(夏春谷); Sun W(孙伟); Sun W(孙伟)
推荐引用方式 GB/T 7714	Xia CG,Sun W,Sun W,et al. Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode[J]. Dalton Transactions,2008:5957-5961.
APA	夏春谷,孙伟,孙伟,&胡斌.(2008).Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode.Dalton Transactions,5957-5961.
MLA	夏春谷,et al."Unexpected formation of novel organometallic hetero-cation crystals with a rare coordination mode".Dalton Transactions (2008):5957-5961.