Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}]

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	Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}]
	Xia CG(夏春谷); Xia CG(夏春谷); Hu B(胡斌)
刊名	JOURNAL OF CHEMICAL RESEARCH
	2008
页码	322-323
关键词	homometallic chiral cluster enantioseparation acetylferrocenyl-thiosemicarbazone X-ray structure
ISSN号	0308-2342
通讯作者	夏春谷
中文摘要	Reaction of Ru3(CO)12 with the thio-Schiff base ligand acetylferrocenyl-thiosemicarbazone provides a one-step synthesis of the chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}] as a racemic mixture. One molecule of thiosemicarbazone was consumed in the cluster formation process, in which the ligand was deprotonated and acted as a bidentate N, S donor as well as bridging. The title cluster has been characterised by NMR, IR, HPLC and an X-ray structure determination.
学科主题	清洁催化与生物转化
收录类别	SCI
资助信息	the National Science Fund for Distinguished Young Scholars of China (No. 20625308)
语种	英语
公开日期	2012-11-09
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/1961]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xia CG(夏春谷); Xia CG(夏春谷)
推荐引用方式 GB/T 7714	Xia CG,Xia CG,Hu B. Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}][J]. JOURNAL OF CHEMICAL RESEARCH,2008:322-323.
APA	夏春谷,夏春谷,&胡斌.(2008).Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}].JOURNAL OF CHEMICAL RESEARCH,322-323.
MLA	夏春谷,et al."Synthesis, crystal structure, and enantioseparation of a homometallic, chiral cluster [Ru3(CO)9{1,2-μ-FcC(CH3) = NNC(S)NHCH3}]".JOURNAL OF CHEMICAL RESEARCH (2008):322-323.