The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > OSSO国家重点实验室

	The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope
	Xia CG(夏春谷); Sun W(孙伟); Sun W(孙伟)
刊名	Tetrahedron: Asymmetry
	2008
卷号	19 页码:2359-2362
ISSN号	0957-4166
通讯作者	夏春谷 ; 孙伟
中文摘要	A series of chiral Mn(Salen) complexes have been synthesized and submitted to the kinetic resolution of secondary alcohols bearing a large hindrance in the biphasic system, which is composed of water and CH2Cl2. After evaluating the appropriate complex, additive, and other conditions, chiral secondary alcohols were obtained with enantiomeric excesses of up to 98.6% in 6 min.
学科主题	清洁催化与生物转化
收录类别	SCI
资助信息	the NSFC (20643008;20625308);the Chinese Academy of Sciences
语种	英语
WOS记录号	WOS:000261992600005
公开日期	2012-11-09
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/1921]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xia CG(夏春谷); Sun W(孙伟); Sun W(孙伟)
推荐引用方式 GB/T 7714	Xia CG,Sun W,Sun W. The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope[J]. Tetrahedron: Asymmetry,2008,19:2359-2362.
APA	夏春谷,孙伟,&孙伟.(2008).The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope.Tetrahedron: Asymmetry,19,2359-2362.
MLA	夏春谷,et al."The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope".Tetrahedron: Asymmetry 19(2008):2359-2362.