Chiral Heterodisulfoxide Ligands in Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Chromenones

	Chiral Heterodisulfoxide Ligands in Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Chromenones
	Han, Fuzhong ; Chen, Guihua ; Zhang, Xiangyang ; Liao, Jian
刊名	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
	2011
期号	16 页码:2928-2931
关键词	Sulfur Ligand design Chromenones Boron Michael addition
ISSN号	1434-193X
通讯作者	Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China.
产权排序	2
英文摘要	A new family of benzene-based chiral heterodisulfoxide ligands L1-L5 was synthesized in a single step. These disulfoxide ligands were applied in the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to chromenones. The addition of diverse arylboronic acids to chromenones proceeds smoothly in up to 70% yield with up to 95% ee.
学科主题	Chemistry
收录类别	SCI
资助信息	National Natural Science Foundation of China (NSFC)[21072186, 20872139]; West Light Foundation of CAS; National Basic Research Program of China (973 Program)[2010CB833300]; Chengdu Institute of Biology, CAS[Y0B1051100]
语种	英语
WOS记录号	WOS:000291563200006
公开日期	2012-11-09
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/23545]
专题	成都生物研究所_天然产物研究
推荐引用方式 GB/T 7714	Han, Fuzhong,Chen, Guihua,Zhang, Xiangyang,et al. Chiral Heterodisulfoxide Ligands in Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Chromenones[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2011(16):2928-2931.
APA	Han, Fuzhong,Chen, Guihua,Zhang, Xiangyang,&Liao, Jian.(2011).Chiral Heterodisulfoxide Ligands in Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Chromenones.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(16),2928-2931.
MLA	Han, Fuzhong,et al."Chiral Heterodisulfoxide Ligands in Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Chromenones".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .16(2011):2928-2931.