Chiral Phosphoric Acid Catalyzed Enantioselective Allylation of Aldehydes with Allyltrichlorosilane

	Chiral Phosphoric Acid Catalyzed Enantioselective Allylation of Aldehydes with Allyltrichlorosilane
	Cheng Ke ; Fan Tiantian ; Sun Jian
刊名	CHINESE JOURNAL OF CHEMISTRY
	2011
卷号	29 期号:8 页码:1669-1671
关键词	phosphoric acid allylation aldehydes allyltrichlorosilane
ISSN号	1001-604X
通讯作者	Sun, J (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Sichuan, Peoples R China.
产权排序	1
英文摘要	Easily accessible chiral phosphoric acid 1b has been applied as efficient organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilane. In the presence of 20 mol% of 1b, the allylation of a broad range of aldehydes proceeded smoothly to give the corresponding homoallylic alcohol with up to 87% ee and 97% yield.
学科主题	Chemistry
收录类别	SCI
资助信息	National Natural Science Foundation of China[20732006, 20972152]
语种	英语
WOS记录号	WOS:000294779400018
公开日期	2012-11-09
内容类型	期刊论文
源URL	[http://210.75.237.14/handle/351003/23537]
专题	成都生物研究所_天然产物研究
推荐引用方式 GB/T 7714	Cheng Ke,Fan Tiantian,Sun Jian. Chiral Phosphoric Acid Catalyzed Enantioselective Allylation of Aldehydes with Allyltrichlorosilane[J]. CHINESE JOURNAL OF CHEMISTRY,2011,29(8):1669-1671.
APA	Cheng Ke,Fan Tiantian,&Sun Jian.(2011).Chiral Phosphoric Acid Catalyzed Enantioselective Allylation of Aldehydes with Allyltrichlorosilane.CHINESE JOURNAL OF CHEMISTRY,29(8),1669-1671.
MLA	Cheng Ke,et al."Chiral Phosphoric Acid Catalyzed Enantioselective Allylation of Aldehydes with Allyltrichlorosilane".CHINESE JOURNAL OF CHEMISTRY 29.8(2011):1669-1671.