Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12

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	Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12
	Xia CG(夏春谷); Hu B(胡斌); Xia CG(夏春谷)
刊名	Journal of Cluster Science
	2008
卷号	19 页码:615-621
关键词	Trinuclear metal cluster Fischer-type carbene Thiocarboxamido ligand Crystal structure
ISSN号	1040-7278
通讯作者	夏春谷
中文摘要	Two new Fischer-type carbene-containing trinuclear transition-metal clusters: (l3-S)Co3(CO)7[l, g2-SCNEt2] 1 and CoRu2(CO)9[l3, g2-SCNEt2] 2 were obtained by the reaction of tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12. These clusters contain thiocarboxamido ligand in different coordination modes. The thiocarboxamido ligand served as monometalated or dimetalated sulfur(diethy1amino) carbene ligand in these clusters. Clusters 1 and 2 were characterized by IR, 1H NMR, and single-crystal X-ray diffraction.
学科主题	清洁催化与生物转化
收录类别	SCI
资助信息	the National Science Fund for Distinguished Young Scholars of China (No. 20625308)
语种	英语
公开日期	2012-09-21
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/600]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xia CG(夏春谷); Xia CG(夏春谷)
推荐引用方式 GB/T 7714	Xia CG,Hu B,Xia CG. Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12[J]. Journal of Cluster Science,2008,19:615-621.
APA	夏春谷,胡斌,&夏春谷.(2008).Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12.Journal of Cluster Science,19,615-621.
MLA	夏春谷,et al."Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12".Journal of Cluster Science 19(2008):615-621.