Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures

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	Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures
	Xia CG(夏春谷); Xia CG(夏春谷); Hu XX(胡霄雪); Hu B(胡斌)
刊名	European Journal of Inorganic Chemistry
	2008
页码	5617-5621
关键词	Ruthenium Carbonyl ligands Multinuclear compounds Structure elucidation
ISSN号	1434-1948
通讯作者	夏春谷
中文摘要	Reaction of acetylferrocene thiosemicarbazone [L] with Ru3(CO)12 was investigated. Two new complexes, Ru3(CO)9-[L-H] (1) and Ru2(CO)4[L]2 (2) were isolated. They were characterized by IR, 1H NMR, and 13C NMR spectroscopic analysis. The crystal structures of 1 and 2 were also determined. In trinuclear cluster 1, the acetylferrocene thiosemicarbazone ligand was deprotonated and acted as an N,S-chelating ligand as well as a sulfur bridge. Dinuclear compound 2 is the first bis(cycloruthenated acetylferrocene thiosemicarbazone) carbonyl derivative. This complex contains two ruthenium atoms in a dinuclear structure with a Cferrocene, N, S2, and (CO)2 coordination sphere for each ruthenium atom, as both L ligands act as a Cferrocene, N, S2 chelate, and sulfur bridge. The behavior of 1 and 2 under electrospray ionization mass spectrometry (ESI-MS) was studied and the key intermediate Ru(CO)2[L-H] (3) in the formation of 2 was directly detected in the reaction solution.
学科主题	清洁催化与生物转化
收录类别	SCI
资助信息	the National Science Fund for Distinguished Young Scholars of China (No. 20625308)
语种	英语
WOS记录号	WOS:000262312100009
公开日期	2012-09-21
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/563]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xia CG(夏春谷); Xia CG(夏春谷)
推荐引用方式 GB/T 7714	Xia CG,Xia CG,Hu XX,et al. Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures[J]. European Journal of Inorganic Chemistry,2008:5617-5621.
APA	夏春谷,夏春谷,胡霄雪,&胡斌.(2008).Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures.European Journal of Inorganic Chemistry,5617-5621.
MLA	夏春谷,et al."Reaction of (Carbonyl)triruthenium with Acetylferrocene Thiosemicarbazone: Synthesis, X-ray Diffraction, and Insight into the Solution Structures".European Journal of Inorganic Chemistry (2008):5617-5621.