2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization | |
Zhang M(张民) ; Zhang WJ(张文娟) ; 肖田鹏飞 ; Xiang JF(向俊峰) ; Hao X(郝项) ; Sun WH(孙文华) | |
刊名 | J. Mol. Catal. A: Chem. |
2010 | |
卷号 | 320页码:92-96 |
关键词 | 2-Ethyl-ketimino-1 Iron(II) complexes Ethylene oligomerization 10-phenanthroline |
ISSN号 | 1381-1169 |
通讯作者 | 孙文华 |
中文摘要 | A series of 2-(1-aryliminopropyl)-1,10-phenanthrolines (L1–L7) and their corresponding iron(II) chlorides (Fe1–Fe7) are synthesized and characterized by elemental and spectroscopic analyses. The molecular structures of 2-[1-(2,6-diisopropy1phenylimino)propyl]-1,10-phenanthroline (L3) and {2-[1-(2,6-diethylphenylimino)propyl]-1,10-phenanthroline}·FeCl2 (Fe2) are determined by the single crystal X-ray diffraction. All iron complexes, activated with methylaluminoxane (MAO), exhibit high activities in ethylene oligomerization with high selectivity for -olefins produced. Compared with other 2-iminophenanthrolines, the title complexes show better thermal stability, and their oligomerization products are potentially more useful due to lower contents of butenes and waxes observed. |
学科主题 | 物理化学 |
收录类别 | SCI |
资助信息 | NSFC no. 20674089 |
语种 | 英语 |
WOS记录号 | WOS:000276011600014 |
公开日期 | 2012-09-21 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/476] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
推荐引用方式 GB/T 7714 | Zhang M,Zhang WJ,肖田鹏飞,et al. 2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization[J]. J. Mol. Catal. A: Chem.,2010,320:92-96. |
APA | 张民,张文娟,肖田鹏飞,向俊峰,郝项,&孙文华.(2010).2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization.J. Mol. Catal. A: Chem.,320,92-96. |
MLA | 张民,et al."2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization".J. Mol. Catal. A: Chem. 320(2010):92-96. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论