2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization

CORC > 兰州化学物理研究所 > 中国科学院兰州化学物理研究所 > OSSO国家重点实验室

	2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization
	Liu H(刘浩) ; Zhao WZ(赵炜珍) ; Hao X(郝项) ; Carl Redshaw ; Huang W(黄伟) ; Sun WH(孙文华)
刊名	Organometallics
	2011
卷号	30 页码:2418-2424
ISSN号	0276-7333
通讯作者	孙文华
中文摘要	A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamines (L1 L5) and the nickel(II) dibromide complexes thereof (C1 C5) were synthesized and fully characterized. The molecular structures of representative complexes were determined by single-crystal X-ray diffraction and revealed a distorted-pyramidal geometry at nickel. All nickel(II) procatalysts exhibited very high activity for the polymerization of ethylene, with activities as high as the range of 107 g of PE (mol of Ni) 1 h 1.
学科主题	物理化学
收录类别	SCI
资助信息	the MOST 863 program No. 2009AA033601;C.R. thanks the EPSRC for an overseas travel grant (No. EP/H031855/1)
语种	英语
WOS记录号	WOS:000289501000041
公开日期	2012-09-20
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/405]
专题	兰州化学物理研究所_OSSO国家重点实验室
推荐引用方式 GB/T 7714	Liu H,Zhao WZ,Hao X,et al. 2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization[J]. Organometallics,2011,30:2418-2424.
APA	刘浩,赵炜珍,郝项,Carl Redshaw,黄伟,&孙文华.(2011).2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization.Organometallics,30,2418-2424.
MLA	刘浩,et al."2,6-Dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamine Nickel Dibromides: Synthesis, Characterization, and Ethylene Polymerization".Organometallics 30(2011):2418-2424.