Al2O3 supported Ru catalysts prepared by thermolysis of Ru3(CO)12 for catalytic wet air oxidation

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	Al2O3 supported Ru catalysts prepared by thermolysis of Ru3(CO)12 for catalytic wet air oxidation
	Yu CY(于超英); Hu B(胡斌); Chen GX(陈革新); Zhao PQ(赵培庆)
刊名	Appl. Surf. Sci.
	2011
卷号	257 页码:7727-7731
关键词	Catalytic wet air oxidation Ruthenium carbonyl Isopropyl alcohol Phenol Acetic acids N,N-dimethylformamide
ISSN号	0169-4332
通讯作者	赵培庆
中文摘要	Low loading catalysts Ru/ -Al2O3 and Ru-Ce/ -Al2O3 were prepared by thermolysis of Ru3(CO)12 on - Al2O3. The catalysts were characterized by XPS, XRD and SEM. Two new Ru species (RuA and RuB) were detected during the Ru3(CO)12 decomposition process due to chemical interaction with the active OH groups on the surface of Al2O3 support, and the reduction of them can lead to more dispersed metallic phases. The sample was completely decomposed at 673K in H2, and RuO2 was formed with minor amounts of Ru0.Whenthe temperature was increased to 773K to heat the sample, the ratio of Ru0 to RuO2 increased. However, after the addition of CeO2, only RuO2 was detected on surface. The catalysts exhibited high activities in Catalytic Wet Air Oxidation (CWAO) of different organic compounds at high concentration such as isopropyl alcohol, phenol, acetic acids and N,N-dimethylformamide, which is attributed to the better dispersion of Ru particles and the addition of CeO2 further enhanced number of effectively active sites on the cluster-derived catalyst surface.
学科主题	物理化学
收录类别	SCI
语种	英语
公开日期	2012-09-20
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/358]
专题	兰州化学物理研究所_OSSO国家重点实验室兰州化学物理研究所_ERC国家工程研究中心
通讯作者	Zhao PQ(赵培庆)
推荐引用方式 GB/T 7714	Yu CY,Hu B,Chen GX,et al. Al2O3 supported Ru catalysts prepared by thermolysis of Ru3(CO)12 for catalytic wet air oxidation[J]. Appl. Surf. Sci.,2011,257:7727-7731.
APA	于超英,胡斌,陈革新,&赵培庆.(2011).Al2O3 supported Ru catalysts prepared by thermolysis of Ru3(CO)12 for catalytic wet air oxidation.Appl. Surf. Sci.,257,7727-7731.
MLA	于超英,et al."Al2O3 supported Ru catalysts prepared by thermolysis of Ru3(CO)12 for catalytic wet air oxidation".Appl. Surf. Sci. 257(2011):7727-7731.