Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor | |
Yang XJ(杨晓娟); Huang XJ(黄晓卷) | |
刊名 | Z. Anorg. Allg. Chem. |
2011 | |
卷号 | 637页码:2306-2311 |
关键词 | Tripodal tris-urea receptors Ferrocene Anion binding Protonation NMR spectroscopy |
ISSN号 | 0044-2313 |
通讯作者 | 吴彪 |
中文摘要 | Two anion complexes of a tripodal tris(ferrocenylurea) receptor (L), (LH)·CF3SO3 (1) and (LH)·HSO4 (2), were obtained from L and triflic acid or sulfuric acid, respectively. Crystal structural analyses show that the receptor in the two 1:1 (host/guest) complexes isprotonated (on the bridgehead tertiary amine), and the CF3SO3 – or HSO4 – anion is located outside the tripodal cavity and anchored by the urea and CH groups of the receptor by hydrogen bonds. 1H NMR spectroscopic studies confirmed the binding mode in solution. |
学科主题 | 金属有机 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (20872149) |
语种 | 英语 |
WOS记录号 | WOS:000298478600039 |
公开日期 | 2012-09-20 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/322] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_ERC国家工程研究中心 |
推荐引用方式 GB/T 7714 | Yang XJ,Huang XJ. Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor[J]. Z. Anorg. Allg. Chem.,2011,637:2306-2311. |
APA | 杨晓娟,&黄晓卷.(2011).Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor.Z. Anorg. Allg. Chem.,637,2306-2311. |
MLA | 杨晓娟,et al."Anion Binding of a Protonated Tripodal Tris(ferrocenylurea) Receptor".Z. Anorg. Allg. Chem. 637(2011):2306-2311. |
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