Releasing H2 from Amidoboranes and Derivatives

	Releasing H2 from Amidoboranes and Derivatives
	Chen P(陈萍)
	2011
会议名称	low carbon earth summit 2011
会议日期	2011-10-19
会议地点	大连
其他题名	硼烷酰胺基及其衍生物的氢气排放
页码	35-0
通讯作者	陈萍
中文摘要	recent researches show that reacting alkali or alkali earth metal hydride (lih, nah, or cah2) with ab produces amidoborane with improved dehydrogenation properties. lithium amidoborane (liab),1 sodium amidoborane (naab)1 and calcium amidoborane (caab)2, can release ca. 10.9 wt%, 7.5 wt% and 8.0 wt% of h2 at moderate temperatures, respectively. in this presentation, we report the development of a new type of ternary amidoboranes and amidoborane ammoniates. the structures and thermal decomposition of those chemicals have been investigated by means of xrd, tpd, dsc and volumetric release. it was observed that hydrogen desorption from amidoborane ammoniates started at temperatures below 70°c and more than 8 wt% of h2 can be released at 150 °c.
合作状况	分会特邀报告
会议主办者	国家外国专家局国外人才信息研究中心
会议录	low carbon earth summit 2011
会议录出版者	待补充
会议录出版地	待补充
学科主题	物理化学
语种	中文
内容类型	会议论文
源URL	[http://159.226.238.44/handle/321008/116147]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
推荐引用方式 GB/T 7714	Chen P. Releasing H2 from Amidoboranes and Derivatives[C]. 见:low carbon earth summit 2011. 大连. 2011-10-19.