DIRECT CATALYTIC CONVERSION OF BIOMASS INTO GLYCOLS USING TUNGSTEN-BASED CATALYSTS | |
Wang AQ(王爱琴) ; Zheng MY(郑明远) ; Ji N(纪娜) ; Zhang YH(张艳华) ; Huang YQ(黄延强) ; Zhang T(张涛) | |
2011 | |
会议名称 | 240th american chemical society national meeting&exposition |
会议日期 | 2010-8-22 |
会议地点 | 波士顿 |
页码 | 116-0 |
通讯作者 | 张涛 |
中文摘要 | introduction the world is currently facing two important issues in fossil energy consumption, i.e., depletion of fossil energy resources and climate warming caused by co2 emission. using renewable resources to obtain sustainable energy supplies and chemicals is required for a prosperous world in the future. biomass originates from plants photosynthesis with huge annual production. the sugar polymers contained in biomass are suitable platforms for the production of renewable fuels and chemicals, and has gained much attention in their transformations [1-6]. different from many works where cellulose is first hydrolyzed into glucose by mineral acids and then transformed into other chemicals by fermentation or catalysis, our group recently discovered that cellulose can be directly converted into ethylene glycol (eg) at yields of 60-75% by using tungsten-based catalysts under hydrothermal hydrogenation conditions [7-9]. moreover, when the feed was changed to jerusalem artichoke tuber (jat), which contains 70-90 wt% fructan in the dried biomass, 1,2-propylene glycol (1,2-pg) was formed as the main product [10]. ethylene glycol and propylene glycol are important bulk chemicals, which are dominantly produced from petroleum resources at present. our work provides a novel way for biomass conversion to chemicals and thereby reduces the dependence on petroleum. in this contribution, we report our recent progress in the biomass conversion to eg and pg. |
合作状况 | 分会特邀报告 |
会议主办者 | acs |
会议录 | 论文集
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会议录出版者 | 待补充 |
会议录出版地 | 待补充 |
学科主题 | 物理化学 |
内容类型 | 会议论文 |
源URL | [http://159.226.238.44/handle/321008/115891] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
推荐引用方式 GB/T 7714 | Wang AQ,Zheng MY,Ji N,et al. DIRECT CATALYTIC CONVERSION OF BIOMASS INTO GLYCOLS USING TUNGSTEN-BASED CATALYSTS[C]. 见:240th american chemical society national meeting&exposition. 波士顿. 2010-8-22. |
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