Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex

	Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex
	Ke HS ; Zhao L ; Tang JK
刊名	journal of coordination chemistry
	2011
卷号	64 期号:11 页码:2020-2027
关键词	ALKOXO BIS((N N-DIMETHYLFORMAMIDE) UTEROFERRIN TRINUCLEAR ZINC(II) LIGANDS DONORS
ISSN号	0095-8972
通讯作者	tang jk
中文摘要	a new dinuclear nickel complex, [ni(2)(ii)(h(1.5)l)(2)](clo(4)) center dot 2ch(3)oh center dot h(2)o (1) (h(3)l 1,3-bis(salicylamino)-2-propanol), was synthesized and characterized by single-crystal x-ray diffraction, ir spectra, elemental analysis, and magnetic measurements. in contrast to commonly observed alcoholic oxygen bridges in previously reported dinuclear complexes, single-crystal x-ray studies reveal that the h(3)l is highly distorted and links two ni(ii) through the phenoxo oxygens of the ligands forming a [ni(2)o(2)] core. the remarkable distortion of the ligand brings the two non-bridging phenol groups from different ligands close to share one hydrogen, keeping charge neutrality of the complex. magnetic studies indicate that an overall antiferromagnetic interaction is operative between the metal centers.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000291543400016
公开日期	2012-06-11
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/44980]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Ke HS,Zhao L,Tang JK. Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex[J]. journal of coordination chemistry,2011,64(11):2020-2027.
APA	Ke HS,Zhao L,&Tang JK.(2011).Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex.journal of coordination chemistry,64(11),2020-2027.
MLA	Ke HS,et al."Synthesis, crystal structure, and magnetic properties of a phenoxo-bridged dinuclear nickel(II) complex".journal of coordination chemistry 64.11(2011):2020-2027.