Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study

	Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study
	Han YY ; Jiang W
刊名	journal of physical chemistry b
	2011
卷号	115 期号:10 页码:2167-2172
关键词	HOLLOW-SPHERE TRANSITION MICROPHASE FORMATION POLYMERIC MICELLES BONDED POLYMERS JANUS MICELLES COMMON SOLVENT PHASE-BEHAVIOR B-C BLENDS MICELLIZATION
ISSN号	1520-6106
通讯作者	jiang w
中文摘要	monte carlo simulation was used to study the self-assembly of the ab/bc diblock copolymer mixture based on hydrogen bonding (h-bonding) in a selective solvent. the simulative results indicate that the self-assembled micelle structure is a function of the intensity of the associative interaction (epsilon(hb)) and the directional dependency (p(hb)) of h-bonding, and the intrinsic repulsive interaction (epsilon(ac)) between a and c blocks. the janus micelles, mixed micelles (micelles with a uniform mixing of different blocks in corona) and pure micelles (micelles with either ab or bc diblock copolymers) are obtained through the adjustment of epsilon(hb) and epsilon(ac). moreover, the simulative results reveal that decreasing directional dependency (p(hb)) and increasing h-bonding interaction (epsilon(hb)) has an equivalent effect on the micelle structure and h-bonding association for the ab/bc diblock copolymer mixture in a selective solvent.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000288113300005
公开日期	2012-06-11
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/44757]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Han YY,Jiang W. Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study[J]. journal of physical chemistry b,2011,115(10):2167-2172.
APA	Han YY,&Jiang W.(2011).Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study.journal of physical chemistry b,115(10),2167-2172.
MLA	Han YY,et al."Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study".journal of physical chemistry b 115.10(2011):2167-2172.