Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes

	Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes
	Feng T ; Peng HM ; Yao YM ; Zhang Y ; Shen Q ; Cheng YX
刊名	chinese science bulletin
	2011
卷号	56 期号:14 页码:1471-1475
关键词	RING-OPENING POLYMERIZATION STRUCTURAL-CHARACTERIZATION LIGANDS REACTIVITY CATALYSTS NICKEL BEARING LACTIDE
ISSN号	1001-6538
通讯作者	yao ym
中文摘要	the synthesis, characterization and luminescent properties of aluminum complexes containing a dianionic n-aryloxo functionalized beta-ketoiminate ligand are presented. 4-(2-hydroxy-5-r-phenyl)imino-2-pentanone (r = me, l(1)h(2); r = tert-butyl, l(2)h(2)) ligands reacted with alet(3) in tetrahydrofuran to give the aluminum complexes (l(1)alet)(2) (1) and (l(2)alet)(2) (2) in reasonable isolated yields. x-ray diffraction revealed that complexes 1 and 2 have solvent-free centrosymmetric dimeric structures, and each aluminum center has distorted trigonal bipyramidal geometry. at room temperature, complexes 1 and 2 exhibit blue photoluminescence in acetonitrile with maximum emission wavelengths of 419 and 413 nm, respectively.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000290274400009
公开日期	2012-06-11
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/44678]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Feng T,Peng HM,Yao YM,et al. Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes[J]. chinese science bulletin,2011,56(14):1471-1475.
APA	Feng T,Peng HM,Yao YM,Zhang Y,Shen Q,&Cheng YX.(2011).Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes.chinese science bulletin,56(14),1471-1475.
MLA	Feng T,et al."Synthesis, characterization and photoluminescence of aluminum N-aryloxo functionalized beta-ketoiminate complexes".chinese science bulletin 56.14(2011):1471-1475.