Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane

	Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane
	Lin SY ; Xu GF ; Zhao L ; Guo YN ; Tang JK ; Wang QL ; Liu GX
刊名	inorganica chimica acta
	2011
卷号	373 期号:1 页码:173-178
关键词	MAGNETIC-PROPERTIES METAL-COMPLEXES SINGLE-CRYSTAL GROUND-STATE SCHIFF-BASE DFT METHODS CLUSTER WATER RELAXATION HONEYCOMB
ISSN号	0020-1693
通讯作者	tang jk
中文摘要	three new tetranuclear nickel(ii) complexes of general formula [ni(4)(l)(2)(n(3))(2)(ch(3)coo)(2)(ch(3)o)(2)](2)center dot xch(3)oh center dot yh(2)o (hl = hl(1), hl(2) and hl(3); x = 0, y = 1 for 1; x = 2, y = 0 for 2 and x = 2, y = 4 for 3) were synthesized and characterized by single crystal x-ray diffraction and magnetic measurements. single crystal x-ray studies reveal that all three complexes exhibit similar tetranuclear face-shared defective double-cubane structure, having azido-, alk/phenoxido- and acetato-bridges. magnetic susceptibility measurements on the complexes in the range of 300-2 k indicate ferromagnetic coupling between the metal ions. the slightly different magnetic behaviors observed are probably caused by subtle structural differences between the respective [ni(4)o(4)n(2)] cores induced by ligand variation. (c) 2011 elsevier b. v. all rights reserved.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000291244600025
公开日期	2012-06-08
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/44470]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Lin SY,Xu GF,Zhao L,et al. Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane[J]. inorganica chimica acta,2011,373(1):173-178.
APA	Lin SY.,Xu GF.,Zhao L.,Guo YN.,Tang JK.,...&Liu GX.(2011).Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane.inorganica chimica acta,373(1),173-178.
MLA	Lin SY,et al."Three azido-, alk/phenoxido- and acetato-bridged tetranuclear nickel complexes featuring defective double-cubane".inorganica chimica acta 373.1(2011):173-178.