Architecture of electrospun carbon nanofibers-hydroxyapatite composite and its application act as a platform in biosensing | |
Cui K ; Song YH ; Guo QH ; Xu FG ; Zhang Y ; Shi Y ; Wang L ; Hou HQ ; Li Z | |
刊名 | sensors and actuators b-chemical
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2011 | |
卷号 | 160期号:1页码:435-440 |
关键词 | NANOTUBES-MODIFIED ELECTRODE CYTOCHROME-C DIRECT ELECTROCHEMISTRY GLUCOSE BIOSENSOR HORSERADISH-PEROXIDASE NANO-HYDROXYAPATITE HYDROGEN-PEROXIDE NANOCOMPOSITE NANOPARTICLES FILM |
ISSN号 | 0925-4005 |
通讯作者 | wang l |
中文摘要 | a biofunctional hybrid composite was constructed by assembling hydroxyapatite (ha) onto carboxylic group-functionalized carbon nanofibers (fcnfs). the fcnfs was obtained from acid treatment of carbon nanofibers (cnfs) which were synthesized by the combination of electrospinning and thermal treatment processes. the obtained carbon nanofibers-hydroxyapatite composite (fcnfs-ha) was characterized by scanning electron microscopy (sem), x-ray diffraction (xrd) and ftir spectroscopy. cytochrome c (cyt c) was successfully immobilized in this three-dimensional fcnfs-ha composite and the electron transfer rate constant (k(s)) was evaluated to be 3.66 s(-1) according to laviron's equation. and the surface coverage (gamma*) was estimated to be 8.1 x 10(-10) mol cm(-2). cyt c immobilized in fcnfs-ha composite exhibited a good electrocatalytic activity towards the reduction of hydrogen peroxide (h(2)o(2)). the catalytic current is linear to the h(2)o(2) concentration in the range of 2.0 mu m to 8.7 mm (r=0.9996: n = 28), and the detection limit was 0.3 mu m based on the criterion of a signal-to-noise ratio of 3. (c) 2011 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000298768100062 |
公开日期 | 2012-06-07 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/44171] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Cui K,Song YH,Guo QH,et al. Architecture of electrospun carbon nanofibers-hydroxyapatite composite and its application act as a platform in biosensing[J]. sensors and actuators b-chemical,2011,160(1):435-440. |
APA | Cui K.,Song YH.,Guo QH.,Xu FG.,Zhang Y.,...&Li Z.(2011).Architecture of electrospun carbon nanofibers-hydroxyapatite composite and its application act as a platform in biosensing.sensors and actuators b-chemical,160(1),435-440. |
MLA | Cui K,et al."Architecture of electrospun carbon nanofibers-hydroxyapatite composite and its application act as a platform in biosensing".sensors and actuators b-chemical 160.1(2011):435-440. |
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