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MECHANISM OF THE VISIBLE LUMINESCENCE IN POROUS SILICON
G. G. Qin ; Y. Q. Jia
刊名Solid State Communications
1993
卷号86期号:9页码:559-563
关键词photoluminescence dioxide sio2
ISSN号0038-1098
中文摘要Highly efficient photoluminescence (PL) in the visible light range has been found in porous Si (PS). The quantum confinement model (QCM) for the PL mechanism although-h explains why the PL energy of PS is in the visible light range, it meets great difficulties in explaining blue and especially red shifts of the PL peak position of PS with varying temperature, pressure, anodic-etching conditions and post-treatments. Considering the rational parts of the previous models and also the contradictions between these models and experimental results, a new model is proposed in this work which explains qualitatively a lot of important experimental results without severe difficulties. We emphasize that there is a lack of nonradiative recombination centers inside the nanoscale Si unit and there is a much greater probability of radiative recombination through luminescence centers outside nanoscale Si units than through band to band transitions inside the nanoscale Si units and these two factors explain why PS has a highly efficient PL. The suggested model may also be applicable to some other Si-based luminescent materials other than PS.
原文出处://WOS:A1993LE32800006
公开日期2012-04-14
内容类型期刊论文
源URL[http://ir.imr.ac.cn/handle/321006/39112]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
G. G. Qin,Y. Q. Jia. MECHANISM OF THE VISIBLE LUMINESCENCE IN POROUS SILICON[J]. Solid State Communications,1993,86(9):559-563.
APA G. G. Qin,&Y. Q. Jia.(1993).MECHANISM OF THE VISIBLE LUMINESCENCE IN POROUS SILICON.Solid State Communications,86(9),559-563.
MLA G. G. Qin,et al."MECHANISM OF THE VISIBLE LUMINESCENCE IN POROUS SILICON".Solid State Communications 86.9(1993):559-563.
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