Laser-induced coloration of WO3 | |
Y. Zhao ; Z. C. Feng ; Y. Liang ; H. W. Sheng | |
刊名 | Applied Physics Letters |
1997 | |
卷号 | 71期号:16页码:2227-2229 |
关键词 | amorphous wo3 films photoelectrolysis electrode light |
ISSN号 | 0003-6951 |
中文摘要 | It has long been recognized that WO3 can be colored through electro-, photo-, and thermo-chromism processes. We report here that WO3 turned to a deep blue color upon just one pulse irradiation of the XeCl excimer laser (lambda = 308 nm, pulse duration = 36 ns, output energy = 100 mJ/pulse). Scanning electron microscopy (SEM) images showed that a melted layer was formed on the surface of the sample. The color change was demonstrated by UV-visible diffuse reflectance. X-ray photoelectron spectroscopy (XPS) showed the partial reduction of WO3 and the appearance of conduction band electrons. Calorimetry measurement results indicated that reoxidation happened at 400-440 degrees C in air. From these experimental results combining with the calculation, it was concluded that the laser-induced coloration is different from ordinary photochromism induced by UV light, and may be attributed to thermochromism. (C) 1997 American Institute of Physics. |
原文出处 | |
公开日期 | 2012-04-14 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/38222] |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Y. Zhao,Z. C. Feng,Y. Liang,et al. Laser-induced coloration of WO3[J]. Applied Physics Letters,1997,71(16):2227-2229. |
APA | Y. Zhao,Z. C. Feng,Y. Liang,&H. W. Sheng.(1997).Laser-induced coloration of WO3.Applied Physics Letters,71(16),2227-2229. |
MLA | Y. Zhao,et al."Laser-induced coloration of WO3".Applied Physics Letters 71.16(1997):2227-2229. |
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