Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5

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	Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5
	Y. Shi ; J. K. Liang ; H. Zhang ; Q. L. Liu ; X. L. Chen ; J. L. Yang ; W. D. Zhuang ; G. H. Rao
刊名	Journal of Solid State Chemistry
	1998
卷号	135 期号:1 页码:43-51
关键词	vibrational-spectra sinhalite
ISSN号	0022-4596
中文摘要	The crystal structure and thermal decomposition process of barium borophosphate BaBPO5 have been studied by a combination of X-ray powder diffraction (XRD) and vibration spectroscopic techniques, The structure of BaBPO5 is refined by Rietveld technique, which indicates that the structure units of this compound are PO4 and BO4 tetrahedra as well as irregular rare earth polyhedra, The thermal decomposition process of BaBPO5 have been observed by the XRD patterns of decomposition samples under a series of heat treatments, The Raman and infrared spectra of the initial compound BaBPO5 and its decomposed products Ba3BP3O12 and Ba2P2O7 showed the variations of the anion groups of boron and phosphorus, Assignments have been deduced from the systematic investigation of natural compounds and isotopic species with the help of isotopic shift data of B-10-B-11. (C) 1998 Academic Press.
原文出处	://WOS:000072523100005
公开日期	2012-04-14
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/37772]
专题	金属研究所_中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. Shi,J. K. Liang,H. Zhang,et al. Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5[J]. Journal of Solid State Chemistry,1998,135(1):43-51.
APA	Y. Shi.,J. K. Liang.,H. Zhang.,Q. L. Liu.,X. L. Chen.,...&G. H. Rao.(1998).Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5.Journal of Solid State Chemistry,135(1),43-51.
MLA	Y. Shi,et al."Crystal structure and thermal decomposition studies of barium borophosphate, BaBPO5".Journal of Solid State Chemistry 135.1(1998):43-51.