EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals | |
W. C. Zheng ; Z. Qing ; X. X. Wu ; M. Yang | |
刊名 | Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy |
2005 | |
卷号 | 61期号:6页码:1243-1246 |
关键词 | local lattice distortion electron paramagnetic resonance (EPR) crystal and ligand-field theory Cr3+ KSc(MoO4)(2) RbIn(MoO4)(2) RbSC(MoO4)(2) electron-paramagnetic resonance superposition-model analysis phase-transitions double molybdates tungstates pressure centers spectra distortions hosts |
ISSN号 | 1386-1425 |
中文摘要 | The calculations of EPR parameters (g factors g(parallel to), g(perpendicular to) and zero-field splitting D) related to the impurity structures have been made from the high-order perturbation formulas for Cr3+ ions in trigonal KSc(MoO4)(2), RbSc(MoO4)(2) and RbSc(MoO4)(2) crystals. It is found that the MO6 octahedra in these crystals change from the trigonal elongation in the pure crystals to the trigonal compression in the impurity centers. The results are discussed. (c) 2004 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-14 |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/35282] |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. C. Zheng,Z. Qing,X. X. Wu,et al. EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals[J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,2005,61(6):1243-1246. |
APA | W. C. Zheng,Z. Qing,X. X. Wu,&M. Yang.(2005).EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals.Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,61(6),1243-1246. |
MLA | W. C. Zheng,et al."EPR parameters and impurity structures for Cr3+ ions in KSC(MoO4)2, RbIn(MoO4)(2) and RbSC(MoO4)(2) crystals".Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 61.6(2005):1243-1246. |
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