Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds

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	Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds
	W. H. Yang ; J. M. Wang ; Z. N. Yang ; T. Pan ; J. Q. Zhang
刊名	Chinese Journal of Chemical Physics
	2005
卷号	18 期号:1 页码:105-112
关键词	Fe(VI) compounds synthesis analysis stability ab initio super-iron battery ferrate potassium electrode bafeo4
ISSN号	1003-7713
中文摘要	In order to understand the physical properties and electrochemical performance of several kinds of Fe(VI) compounds, K2FeO4, BaFeO4, SrFeO4 and K2Sr( FeO4)(2) were synthesized by a chemical method. The appearance, structure, solubility and discharge performance of the four kinds of ferrates were investigated. Studies show that BaFeO4 has better discharge performance. However, it has been found out that other ferrates except for K2FeO4 are unstable. They decompose in dry environment. The quantum ab initio calculation was used to compare the polarization effects of positive ions on FeO42-. Results show that the Fe(VI) compounds become less stable with the increase of the polarization effects.
原文出处	://WOS:000227637900020
公开日期	2012-04-14
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/35172]
专题	金属研究所_中国科学院金属研究所
推荐引用方式 GB/T 7714	W. H. Yang,J. M. Wang,Z. N. Yang,et al. Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds[J]. Chinese Journal of Chemical Physics,2005,18(1):105-112.
APA	W. H. Yang,J. M. Wang,Z. N. Yang,T. Pan,&J. Q. Zhang.(2005).Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds.Chinese Journal of Chemical Physics,18(1),105-112.
MLA	W. H. Yang,et al."Physical properties, electrochemical performance and stability of several kinds of Fe(VI) compounds".Chinese Journal of Chemical Physics 18.1(2005):105-112.