Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br)

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	Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br)
	L. H. Wei ; S. Y. Wu ; Z. H. Zhang ; X. F. Wang ; Y. X. Hu
刊名	Hyperfine Interactions
	2008
卷号	181 期号:1-3 页码:169-177
关键词	Electron paramagnetic resonance (EPR) K(2)PdX(4) (X = Cl Superhyperfine interactions Br) Cu(2+) atomic screening constants square-planar angular distortions liquid-membrane scf functions absorption k2pdcl4 spectra complexes carrier
ISSN号	0304-3843
中文摘要	The superhyperfine parameters T(j) (j = x, y, z) for Cu(2+) in the square-planar K(2)PdX(4) (X = Cl, Br) are theoretically studied from the perturbation formulas of these parameters for an octahedral 3d(9) cluster, by considering both the contributions from the crystal-field and charge-transfer mechanisms. The related molecular orbital coefficients are determined from the cluster approach in a uniform way. Based on one adjustable proportional factor rho for the orbital admixture coefficients, the calculated results of present work show reasonable agreement with the observed values.
原文出处	://WOS:000260281100024
公开日期	2012-04-13
内容类型	期刊论文
源URL	[http://210.72.142.130/handle/321006/33185]
专题	金属研究所_中国科学院金属研究所
推荐引用方式 GB/T 7714	L. H. Wei,S. Y. Wu,Z. H. Zhang,et al. Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br)[J]. Hyperfine Interactions,2008,181(1-3):169-177.
APA	L. H. Wei,S. Y. Wu,Z. H. Zhang,X. F. Wang,&Y. X. Hu.(2008).Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br).Hyperfine Interactions,181(1-3),169-177.
MLA	L. H. Wei,et al."Theoretical study of the superhyperfine parameters for Cu(2+) in K(2)PdX(4) (X = Cl, Br)".Hyperfine Interactions 181.1-3(2008):169-177.