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Effect of SWNTs on the reversible hydrogen storage properties of LiBH4-MgH2 composite
P. J. Wang ; Z. Z. Fang ; L. P. Ma ; X. D. Kang ; P. Wang
刊名International Journal of Hydrogen Energy
2008
卷号33期号:20页码:5611-5616
关键词Hydrogen storage Lithium borohydride MgH2 Single-walled carbon nanotubes Mechanical milling walled carbon nanotubes arc-discharge method ammonia borane hydride dehydrogenation performances kinetics systems li
ISSN号0360-3199
中文摘要Single-walled carbon nanotubes (SWNTs) were mechanically milled with LiBH4/MgH2 mixture, and examined with respect to its effect on the reversible dehydrogenation properties of the Li-Mg-B-H system. Experimental results show that the addition of SWNTs results in an enhanced dehydriding rate and improved cyclic stability of the LiBH4/MgH2 composite. For example, the LiBH4/MgH2 composite with 10 wt% purified SWNTs additive can release nearly 10 wt% hydrogen within 20 min at 450 degrees C, with an average dehydriding rate over 2 times faster than that of the neat LiBH4/MgH2 sample. Based on the results of phase analysis and a series of designed experiments, the mechanism underlying the observed property improvement was discussed. (c) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
原文出处://WOS:000261009000039
公开日期2012-04-13
内容类型期刊论文
源URL[http://210.72.142.130/handle/321006/33142]  
专题金属研究所_中国科学院金属研究所
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GB/T 7714
P. J. Wang,Z. Z. Fang,L. P. Ma,et al. Effect of SWNTs on the reversible hydrogen storage properties of LiBH4-MgH2 composite[J]. International Journal of Hydrogen Energy,2008,33(20):5611-5616.
APA P. J. Wang,Z. Z. Fang,L. P. Ma,X. D. Kang,&P. Wang.(2008).Effect of SWNTs on the reversible hydrogen storage properties of LiBH4-MgH2 composite.International Journal of Hydrogen Energy,33(20),5611-5616.
MLA P. J. Wang,et al."Effect of SWNTs on the reversible hydrogen storage properties of LiBH4-MgH2 composite".International Journal of Hydrogen Energy 33.20(2008):5611-5616.
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