Lithium zincopyrophosphate, Li(2)Zn(3)(P(2)O(7))(2) | |
L. N. Ji ; H. W. Ma ; J. K. Liang | |
刊名 | Acta Crystallographica Section C-Crystal Structure Communications |
2009 | |
卷号 | 65页码:I30-I32 |
关键词 | zinc phosphate polymorph zno |
ISSN号 | 0108-2701 |
中文摘要 | The title compound, dilithium(I) trizinc(II) bis[diphosphate(4-)], is the first quaternary lithium zincopyrophosphate in the Li-Zn-P-O system. It features zigzag chains running along c, which are built up from edge-sharing [ZnO(5)] trigonal bipyramids. One of the two independent Zn sites is fully occupied, whereas the other is statistically disordered by Zn(2+) and Li(+) cations, although the two Zn sites have similar coordination environments. Li(+) cations occupy a four-coordinated independent site with an occupancy factor of 0.5, as well as being disordered on the partially occupied five-coordinated Zn site with a Zn(2+)/Li(+) ratio of 1:1. |
原文出处 | |
公开日期 | 2012-04-13 |
内容类型 | 期刊论文 |
源URL | [http://210.72.142.130/handle/321006/31991] |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | L. N. Ji,H. W. Ma,J. K. Liang. Lithium zincopyrophosphate, Li(2)Zn(3)(P(2)O(7))(2)[J]. Acta Crystallographica Section C-Crystal Structure Communications,2009,65:I30-I32. |
APA | L. N. Ji,H. W. Ma,&J. K. Liang.(2009).Lithium zincopyrophosphate, Li(2)Zn(3)(P(2)O(7))(2).Acta Crystallographica Section C-Crystal Structure Communications,65,I30-I32. |
MLA | L. N. Ji,et al."Lithium zincopyrophosphate, Li(2)Zn(3)(P(2)O(7))(2)".Acta Crystallographica Section C-Crystal Structure Communications 65(2009):I30-I32. |
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