Analysis of Ground-State Zero-Field Splitting for Mn(2+) in ZnNbOF(5)center dot 6(H(2)O) and CoNbOF(5)center dot 6(H(2)O)

CORC > 金属研究所 > 中国科学院金属研究所

	Analysis of Ground-State Zero-Field Splitting for Mn(2+) in ZnNbOF(5)center dot 6(H(2)O) and CoNbOF(5)center dot 6(H(2)O)
	J. F. Li ; X. Y. Kuang
刊名	Chinese Physics Letters
	2011
卷号	28 期号:6
关键词	phase-transition ions complexes crystals spectra fe-3+ epr
ISSN号	0256-307X
中文摘要	The electron paramagnetic resonance spectra of trigonal Mn(2+) centers in ZnNbOF(5)center dot 6(H(2)O) and CoNbOF(5)center dot 6(H(2)O) crystals are studied on the basis of the complete energy matrices for a d(5) configuration ion in a trigonal ligand field. It is demonstrated that the local lattice structure around a trigonal Mn(2+) center has an elongation distortion along the crystalline c(3) axis, and when Mn(2+) is doped in the ZnNbOF(5)center dot 6(H(2)O) and CoNbOF(5)center dot 6(H(2)O) crystals, there is a similar local distortion. From the EPR calculation, the local lattice structure parameters for trigonal Mn(2+) centers in ZnNbOF(5)center dot 6(H(2)O) and CoNbOF(5)center dot 6(H(2)O) are determined.
原文出处	://WOS:000291243400063
公开日期	2012-04-13
内容类型	期刊论文
源URL	[http://210.72.142.130/handle/321006/30467]
专题	金属研究所_中国科学院金属研究所
推荐引用方式 GB/T 7714	J. F. Li,X. Y. Kuang. Analysis of Ground-State Zero-Field Splitting for Mn(2+) in ZnNbOF(5)center dot 6(H(2)O) and CoNbOF(5)center dot 6(H(2)O)[J]. Chinese Physics Letters,2011,28(6).
APA	J. F. Li,&X. Y. Kuang.(2011).Analysis of Ground-State Zero-Field Splitting for Mn(2+) in ZnNbOF(5)center dot 6(H(2)O) and CoNbOF(5)center dot 6(H(2)O).Chinese Physics Letters,28(6).
MLA	J. F. Li,et al."Analysis of Ground-State Zero-Field Splitting for Mn(2+) in ZnNbOF(5)center dot 6(H(2)O) and CoNbOF(5)center dot 6(H(2)O)".Chinese Physics Letters 28.6(2011).