Guests inducing p-sulfonatocalix[4]arenes into nanocapsule and layer structure | |
Zheng GL ; Fan WQ ; Song SY ; Guo HD ; Zhang HJ | |
刊名 | journal of solid state chemistry |
2010 | |
卷号 | 183期号:6页码:1457-1463 |
关键词 | MIMICKING VIRAL GEOMETRY MOLECULAR CAPSULE SOLID-STATE CONFINEMENT BILAYERS BINDING SULFONATOCALIXARENES ARRAYS IONS |
ISSN号 | 0022-4596 |
通讯作者 | zhang hj |
中文摘要 | reaction of sodium p-sulfonatocalix[4]arene and tbcl(3) in the presence of 2,2'-bipyridine-n,n'-dioxide (bpdo) gives the 2 1 supramolecular nanocapsule [[tb(bpdo)(2) 4h(2)o](3+) boolean and(p-sulfonatocalix[4]arene(4-))2]. which further interacts with the [tb(bpdo)(4)](3+) through charge-assisted pi-stacking interactions forming a channel structure 1 in further investigation, we tried to use the terpyridine-1,1'.1'-trisoxide (tpto) instead of bpdo although we failed to isolate a supramolecular capsules based on the tpto, lanthanide and p-sulfonatocalix[4] arene, a layer structure derived from p-sulfonatocalix[4]arene with an unusual [cu(tpto)(2)](2+) incorporation into the cavity of the calixarene and an outside [cu(tpto)(2)](2+) balancing the charge, has been obtained fluorescence spectra show clearly that compound 1 possesses the luminescence characteristics of tb3+ and the ligand bpdo can sensitize tb3+ ion gas sorption experiment shows the channel structure 1 has highly selective gas sorption properties for water and methanol (c) 2010 published by elsevier inc |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000278750100037 |
公开日期 | 2012-04-26 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43652] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zheng GL,Fan WQ,Song SY,et al. Guests inducing p-sulfonatocalix[4]arenes into nanocapsule and layer structure[J]. journal of solid state chemistry,2010,183(6):1457-1463. |
APA | Zheng GL,Fan WQ,Song SY,Guo HD,&Zhang HJ.(2010).Guests inducing p-sulfonatocalix[4]arenes into nanocapsule and layer structure.journal of solid state chemistry,183(6),1457-1463. |
MLA | Zheng GL,et al."Guests inducing p-sulfonatocalix[4]arenes into nanocapsule and layer structure".journal of solid state chemistry 183.6(2010):1457-1463. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论