Guests inducing p-sulfonatocalix[4]arenes into nanocapsule and layer structure
Zheng GL ; Fan WQ ; Song SY ; Guo HD ; Zhang HJ
刊名journal of solid state chemistry
2010
卷号183期号:6页码:1457-1463
关键词MIMICKING VIRAL GEOMETRY MOLECULAR CAPSULE SOLID-STATE CONFINEMENT BILAYERS BINDING SULFONATOCALIXARENES ARRAYS IONS
ISSN号0022-4596
通讯作者zhang hj
中文摘要reaction of sodium p-sulfonatocalix[4]arene and tbcl(3) in the presence of 2,2'-bipyridine-n,n'-dioxide (bpdo) gives the 2 1 supramolecular nanocapsule [[tb(bpdo)(2) 4h(2)o](3+) boolean and(p-sulfonatocalix[4]arene(4-))2]. which further interacts with the [tb(bpdo)(4)](3+) through charge-assisted pi-stacking interactions forming a channel structure 1 in further investigation, we tried to use the terpyridine-1,1'.1'-trisoxide (tpto) instead of bpdo although we failed to isolate a supramolecular capsules based on the tpto, lanthanide and p-sulfonatocalix[4] arene, a layer structure derived from p-sulfonatocalix[4]arene with an unusual [cu(tpto)(2)](2+) incorporation into the cavity of the calixarene and an outside [cu(tpto)(2)](2+) balancing the charge, has been obtained fluorescence spectra show clearly that compound 1 possesses the luminescence characteristics of tb3+ and the ligand bpdo can sensitize tb3+ ion gas sorption experiment shows the channel structure 1 has highly selective gas sorption properties for water and methanol (c) 2010 published by elsevier inc
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000278750100037
公开日期2012-04-26
内容类型期刊论文
源URL[http://ir.ciac.jl.cn/handle/322003/43652]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Zheng GL,Fan WQ,Song SY,et al. Guests inducing p-sulfonatocalix[4]arenes into nanocapsule and layer structure[J]. journal of solid state chemistry,2010,183(6):1457-1463.
APA Zheng GL,Fan WQ,Song SY,Guo HD,&Zhang HJ.(2010).Guests inducing p-sulfonatocalix[4]arenes into nanocapsule and layer structure.journal of solid state chemistry,183(6),1457-1463.
MLA Zheng GL,et al."Guests inducing p-sulfonatocalix[4]arenes into nanocapsule and layer structure".journal of solid state chemistry 183.6(2010):1457-1463.
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