A new flow injection single-standard calibration method for flame atomic absorption spectrometry based on dilution by microsample dispersion | |
Fang, ZL ; Xu, SK ; Bai, XS | |
刊名 | ANALYTICA CHIMICA ACTA |
1996 | |
卷号 | 326期号:1-3页码:49-55 |
关键词 | flow injection single-standard calibration microsampling atomic absorption spectrometry microsample dispersion |
ISSN号 | 0003-2670 |
通讯作者 | Fang, ZL, ACAD SINICA,INST APPL ECOL,BOX 417,SHENYANG 110015,PEOPLES R CHINA |
中文摘要 | A flow injection (FI) calibration method for flame atomic absorption spectrometry was developed which involved microsampling of a single standard using computer controlled stepper-motor driven peristaltic pumps. The theoretical basis for the method is given, demonstrating the feasibility of utilizing the linear relationship between the reciprocal of the dispersion coefficient (or analyte concentration) and sample volume in Fl systems with dispersion coefficients higher than approximately 30. The errors introduced by loss of linearity at lower dispersions are discussed. Calibration curves constructed by metering microliter volumes of a single standard into a sample loop of approximately 100 mu l were compared statistically to those obtained using a set of standard series within an 8 h working day. No significant differences between the two calibration procedures were observed. |
学科主题 | Chemistry, Analytical |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2011-09-23 |
内容类型 | 期刊论文 |
源URL | [http://210.72.129.5/handle/321005/55689] |
专题 | 沈阳应用生态研究所_沈阳应用生态研究所_期刊论文 |
推荐引用方式 GB/T 7714 | Fang, ZL,Xu, SK,Bai, XS. A new flow injection single-standard calibration method for flame atomic absorption spectrometry based on dilution by microsample dispersion[J]. ANALYTICA CHIMICA ACTA,1996,326(1-3):49-55. |
APA | Fang, ZL,Xu, SK,&Bai, XS.(1996).A new flow injection single-standard calibration method for flame atomic absorption spectrometry based on dilution by microsample dispersion.ANALYTICA CHIMICA ACTA,326(1-3),49-55. |
MLA | Fang, ZL,et al."A new flow injection single-standard calibration method for flame atomic absorption spectrometry based on dilution by microsample dispersion".ANALYTICA CHIMICA ACTA 326.1-3(1996):49-55. |
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