Effect of oxalic acid-leaching levels on structure, color and physico-chemical features of palygorskite | |
Lu YS (卢予沈)1,2; Wang WB (王文波)1; Xu J (许江)1; Wang Q (汪琴)1; Wang AQ (王爱勤)1 | |
刊名 | Applied Clay Science |
2019-12 | |
卷号 | 183期号:无页码:105301 |
关键词 | Palygorskite Organic acid Leaching Morphology Silica |
DOI | 10.1016/j.clay.2019.105301 |
英文摘要 | Palygorskite (Pal) was treated with organic acids to explore effects of acid-leaching levels on its structure, shape of rod crystals, color and physico-chemical features. The leaching behavior of octahedral cations of Pal was studied by evaluating the effect of organic acid types, concentration and reaction time. The results show that oxalic acid (OA) has the strongest ability to leach octahedral metal cations in selected organic acids. OA, having acidity, complexing ability and reduction ability, can be attached to the surface of Pal to promote the leaching reaction, and the position at which the reaction occurs is concentrated on the cylinder surface of the rod crystal. The occupied position of metal cations in the octahedral sheets is the key factor in controlling the leaching of Pal. Mg2+ ions at the edge of the octahedral sheet prefer to leach out, then gradually deepens into the interior octahedral sheet, and Fe3+ and Al3+ ions are leached in turn. When the metal cations are almost completely leached, it means that the octahedral sheets are almost eliminated, at this time, the stacked structure is maintained by the deformed tetrahedron. Compared to conventional inorganic acid leaching methods, organic acid leaching does not destroy the shape of the Pal nanorods. Finally, the one-dimensional amorphous silica nanorods with high SiO2 content of 91.68 wt%, decent rod length, large specific surface area (323 m2/g), high porosity and high whiteness (L* = 86.6, a* = 0.1, b* = 3.2) were obtained by leaching with 1 M OA solution for 120 h, indicating that the non-destructive dissolution of the Pal was achieved. |
URL标识 | 查看原文 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.licp.cn/handle/362003/25391] |
专题 | 兰州化学物理研究所_甘肃省黏土矿物应用重点实验室 |
通讯作者 | Wang WB (王文波); Wang AQ (王爱勤) |
作者单位 | 1.Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-materials and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, PR China 2.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, PR China |
推荐引用方式 GB/T 7714 | Lu YS ,Wang WB ,Xu J ,et al. Effect of oxalic acid-leaching levels on structure, color and physico-chemical features of palygorskite[J]. Applied Clay Science,2019,183(无):105301. |
APA | Lu YS ,Wang WB ,Xu J ,Wang Q ,&Wang AQ .(2019).Effect of oxalic acid-leaching levels on structure, color and physico-chemical features of palygorskite.Applied Clay Science,183(无),105301. |
MLA | Lu YS ,et al."Effect of oxalic acid-leaching levels on structure, color and physico-chemical features of palygorskite".Applied Clay Science 183.无(2019):105301. |
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