Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis | |
Wei, Wei; Wang, Leilei; Bao, Pengli; Shao, Yun; Yue, Huilan; Yang, Daoshan; Yang, Xiaobo; Zhao, Xiaohui; Wang, Hua | |
刊名 | ORGANIC LETTERS
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2018 | |
卷号 | 20期号:22 |
英文摘要 | A novel and efficient visible-light-induced C(sp(2))-H/N-H cross-dehydrogenative coupling (CDC)-amination with both primary and secondary aliphatic amines at room temperature in air is developed. This photocatalytic reaction allows the direct formation of 3-aminoquinoxalin-2(1H)-ones via CDC-amination in the absence of any external oxidant added from outside. Preliminary mechanistic studies reveal that the present reaction proceeds through a radical process. |
内容类型 | 期刊论文 |
源URL | [http://210.75.249.4/handle/363003/59937] ![]() |
专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
推荐引用方式 GB/T 7714 | Wei, Wei,Wang, Leilei,Bao, Pengli,et al. Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis[J]. ORGANIC LETTERS,2018,20(22). |
APA | Wei, Wei.,Wang, Leilei.,Bao, Pengli.,Shao, Yun.,Yue, Huilan.,...&Wang, Hua.(2018).Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis.ORGANIC LETTERS,20(22). |
MLA | Wei, Wei,et al."Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis".ORGANIC LETTERS 20.22(2018). |
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