Stable isotope fractionation of chlorine during evaporation of brine from a saline lake | |
Ma, HZ (Ma Haizhou)[1]; Xiao,YK(Xiao Yingkai)[1]; Luo, CG (Luo Chongguang)[1,3]; He, MY (He Maoyong)[2]; Zhang, YL (Zhang Yanling)[1,3]; Ma, YQ (Ma Yunqi)[1] | |
刊名 | CHINESE SCIENCE BULLETIN
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2012-05-30 | |
卷号 | 57期号:15页码:1833-1843 |
DOI | 10.1007/s11434-012-4994-5 |
文献子类 | 期刊论文 |
英文摘要 | Brine from the saline Qarhan Lake was evaporated at 28 +/- 2A degrees C in a clean environment. Two groups of experiments were conducted; one with complete separation of precipitate and brine at different stages of evaporation, and the other with continuous precipitation during the evaporation. Seventy-nine precipitate and brine samples were collected during the experiments, and the Cl-37 values were determined using an improved thermal ionization mass spectrometry procedure for precise measurement of chlorine isotopes based on Cs2Cl+ ions. Based on the concentrations of Na+, K+, and Mg2+, evaporation was divided into three main precipitation stages as follows: halite dominant, carnallite dominant, and bischofite dominant. The Cl-37(solid) and Cl-37(liquid) values of the precipitate and coexisting brine samples at different stages showed the following characteristics. The precipitates were enriched with Cl-37 relative to the coexisting brine samples, and the Cl-37 of both the precipitate and brine samples decreased gradually during evaporation. The fractionation factors ( (h)) between halite and brine were the highest, followed by that ( (c)) between carnallite and brine, and then that ( (b)) between bischofite and brine. The (c) and (b) values of less than one, which indicate the precipitate is enriched in Cl-35, were found when the evaporation process entered a new stage. However, the Cl-37 values of carnallite, bischofite, and the coexisting brine samples decreased during evaporation. The residual brine is a Cl-35 reservoir. The experimental phenomena were consistent with the Cl-37 values in saline deposits in the literature. Cl-37 can be used as an indicator of brine evaporation processes, which is important in the exploration of sylvinite deposits. |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.ieecas.cn/handle/361006/10155] ![]() |
专题 | 地球环境研究所_加速器质谱中心 |
通讯作者 | Luo, CG (Luo Chongguang)[1,3] |
作者单位 | 1.Graduate University, Chinese Academy of Sciences, Beijing 100049, China 2.CAS Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences,Xining 810008, China; 3.State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi’an 710075, China; |
推荐引用方式 GB/T 7714 | Ma, HZ ,Xiao,YK,Luo, CG ,et al. Stable isotope fractionation of chlorine during evaporation of brine from a saline lake[J]. CHINESE SCIENCE BULLETIN,2012,57(15):1833-1843. |
APA | Ma, HZ ,Xiao,YK,Luo, CG ,He, MY ,Zhang, YL ,&Ma, YQ .(2012).Stable isotope fractionation of chlorine during evaporation of brine from a saline lake.CHINESE SCIENCE BULLETIN,57(15),1833-1843. |
MLA | Ma, HZ ,et al."Stable isotope fractionation of chlorine during evaporation of brine from a saline lake".CHINESE SCIENCE BULLETIN 57.15(2012):1833-1843. |
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