Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions
Zhang, YL (Zhang, Yan-ling)[ 2 ]; Luo, CG (Luo, Chong-guang)[ 3 ]; Xiao, J (Xiao, Jun)[ 1 ]; Zhang, F (Zhang, Fei)[ 1 ]; He, MY (He, Mao-yong)[ 1 ]; Xiao, YK (Xiao, Ying-kai)[ 2 ]; Jin, ZD (Jin, Zhang-dong)[ 1 ]; Ma, YQ (Ma, Yun-qi)[ 2 ]
刊名ANALYTICAL CHEMISTRY
2013-07-02
卷号85期号:13页码:6248-6253
DOI10.1021/ac400066r
文献子类期刊论文
英文摘要

A static double-collector system for accurate, precise, and rapid boron isotope analysis has been established by employing a newly fixed Faraday H3 and H4 cup enabling simultaneously collected Cs2BO2+ ion beams (m/z = 308 and 309) on a Finnigan-MAT Triton thermal ionization mass spectrometer of boron (Triton B). The experimental result indicated that Cs2BO2+ ion beams (m/z = 308 and 309) were simultaneously collected using a fixed Faraday H3 and H4 cup without using the "Zoom Quad" function and reduced accelerating voltage. Furthermore, the method enabled the measurement of samples containing as little as 20 ng of boron. An analysis of the National Institute of Standards and Technology standard reference material (NIST SRM) 951 standard showed external reproducibility (2RSD) of +/- 0.013 parts per thousand, +/- 0.013 parts per thousand, and +/- 0.019 parts per thousand for 100, 50, and 20 ng of boron, respectively. The present method of static multicollection of Cs2BO2+ ions is applicable to a wide field of boron isotopic research that requires high precision and accuracy to analyze samples with low boron concentrations, including pore fluids, foraminifera, rivers, rainwater, and other natural samples.

语种英语
内容类型期刊论文
源URL[http://ir.ieecas.cn/handle/361006/9917]  
专题地球环境研究所_加速器质谱中心
通讯作者He, MY (He, Mao-yong)[ 1 ]
作者单位1.State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences, Xi’an710075, People’s Republic of China;
2.State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002,People’s Republic of China
3.CAS Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining810008, People’s Republic of China;
推荐引用方式
GB/T 7714
Zhang, YL ,Luo, CG ,Xiao, J ,et al. Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions[J]. ANALYTICAL CHEMISTRY,2013,85(13):6248-6253.
APA Zhang, YL .,Luo, CG .,Xiao, J .,Zhang, F .,He, MY .,...&Ma, YQ .(2013).Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions.ANALYTICAL CHEMISTRY,85(13),6248-6253.
MLA Zhang, YL ,et al."Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions".ANALYTICAL CHEMISTRY 85.13(2013):6248-6253.
个性服务
查看访问统计
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。


©版权所有 ©2017 CSpace - Powered by CSpace