Application of point-group bases to f(N)-f(N-1)d transitions of lanthanide and actinide ions doped in crystals

doi:10.1016/j.jpcs.2008.05.021

	Application of point-group bases to f(N)-f(N-1)d transitions of lanthanide and actinide ions doped in crystals
	Ma, Chong-Geng 3,4; Duan, Chang-Kui 5,6; Xia, Shang-Da 3,4; Yin, Min 3,4; Reid, M. F.1,2,5
刊名	JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
	2008-10-01
卷号	69 页码:2578-2583
关键词	Optical materials Inorganic compounds Crystal fields Electronic structure
ISSN号	0022-3697
DOI	10.1016/j.jpcs.2008.05.021
英文摘要	The application of point-group coupling coefficients to the modeling of f(N)<-> f(N-1)d transitions is discussed. There are several possible coupling schemes for the states of the f(N-1)d configuration. Formulae for matrix elements of the Hamiltonian for the f(N-1)d configuration and the relative line strengths for f(N)<-> f(N-1)d transitions are derived. As an example, the f-d absorption spectrum of the crystal Yb2+: SrCl2 is calculated using coupling coefficients based on the software developed by Butler and co-workers, which makes use of the Racah-Wigner calculus. The advantages and disadvantages of various coupling schemes are demonstrated. These coupling schemes are related to the simple model for f-d transitions. (C) 2008 Published by Elsevier Ltd.
资助项目	National Natural Science Foundation of China[10474092] ; City University Research Grant[9360123]
WOS关键词	RARE-EARTH IONS ; RACAH-WIGNER CATEGORY ; SIMPLE-MODEL ; ABSORPTION ; SPECTRUM ; FIELD ; INTENSITIES
WOS研究方向	Chemistry ; Physics
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:000260236100040
资助机构	National Natural Science Foundation of China ; City University Research Grant
内容类型	期刊论文
源URL	[http://119.78.100.186/handle/113462/29202]
专题	中国科学院近代物理研究所
通讯作者	Reid, M. F.
作者单位	1.Univ Canterbury, Dept Phys & Astron, Christchurch 8140, New Zealand 2.Univ Canterbury, MacDiarmid Inst Adv Mat & Nanotechnol, Christchurch 8140, New Zealand 3.Univ Sci & Technol China, Dept Phys, Hefei 230026, Peoples R China 4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China 5.City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China 6.Chongqing Univ Post & Telecommun, Inst Modern Phys, Chongqing 400065, Peoples R China
推荐引用方式 GB/T 7714	Ma, Chong-Geng,Duan, Chang-Kui,Xia, Shang-Da,et al. Application of point-group bases to f(N)-f(N-1)d transitions of lanthanide and actinide ions doped in crystals[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,2008,69:2578-2583.
APA	Ma, Chong-Geng,Duan, Chang-Kui,Xia, Shang-Da,Yin, Min,&Reid, M. F..(2008).Application of point-group bases to f(N)-f(N-1)d transitions of lanthanide and actinide ions doped in crystals.JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS,69,2578-2583.
MLA	Ma, Chong-Geng,et al."Application of point-group bases to f(N)-f(N-1)d transitions of lanthanide and actinide ions doped in crystals".JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 69(2008):2578-2583.